907855
(S)-2-((2-Hydroxy-3-methylbenzyl)amino)-N,N,3-trimethylbutanamide
≥95%
Synonym(s):
Hoveyda aminophenol catalyst
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About This Item
Empirical Formula (Hill Notation):
C15H24N2O2
CAS Number:
Molecular Weight:
264.36
UNSPSC Code:
12352111
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Assay
≥95%
form
powder or chunks
mp
58-60 °C
storage temp.
2-8°C
Application
(S)-2-((2-Hydroxy-3-methylbenzyl)amino)-N,N,3-trimethylbutanamide is an aminophenol organocatalyst developed by the Hoveyda lab for enantioselective addition of allylboron compounds to imines, ketones, and other carbonyls, including polyfluorinated substrates.
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Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Daniel W Robbins et al.
Angewandte Chemie (International ed. in English), 55(33), 9610-9614 (2016-06-09)
A set of broadly applicable methods for efficient catalytic additions of easy-to-handle allyl-B(pin) (pin=pinacolato) compounds to ketones and acyclic α-ketoesters was developed. Accordingly, a large array of tertiary alcohols can be obtained in 60 to >98 % yield and up to
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