804452

Potassium 3-ethoxycarbonylbenzoyltrifluoroborate

• Empirical Formula (Hill Notation): C₁₀H₉BF₃KO₃
• CAS Number: 1622923-42-5
• Molecular Weight: 284.08
• UNSPSC Code: 12352103
• PubChem Substance ID: 329768873
• NACRES: NA.22

Properties

• form: powder
• SMILES string: CCOC(C1=CC=CC(C(B(F)(F)F)=O)=C1)=O.[K]
• InChI: 1S/C10H9BF3O3.K.H/c1-2-17-10(16)8-5-3-4-7(6-8)9(15)11(12,13)14;;/h3-6H,2H2,1H3;;
• InChI key: WJLIBYVPNAKYHP-UHFFFAOYSA-N

Description

Application

Acyltrifluroborates (KAT′s) are bench, air, and moisture stable reagents for rapid, chemoselective amide bond formations with hydroxylamines. These amide bond forming reactions proceed under aqueous conditions, without the need for coupling reagents or protecting groups. This product was introduced in collaboration with the Bode Research Group.

Other Notes

Rapid Ligations with Equimolar Reactants in Water with the Potassium Acyltrifluoroborate (KAT) Amide Formation

Amide-Forming Ligation of Acyltrifluoroborates and Hydroxylamines in Water

Synthesis of Chemically and Configurationally Stable Monofluoro Acylboronates: Effect of Ligand Structure on their Formation, Properties, and Reactivities

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P280 - P304 + P340 + P312 - P305 + P351 + P338 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable