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524328

Sigma-Aldrich

5-Iodosalicylaldehyde

97%

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About This Item

Linear Formula:
lC6H3(OH)CHO
CAS Number:
Molecular Weight:
248.02
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

97%

mp

98-100 °C (lit.)

SMILES string

Oc1ccc(I)cc1C=O

InChI

1S/C7H5IO2/c8-6-1-2-7(10)5(3-6)4-9/h1-4,10H

InChI key

PDFVIWFKGYODKD-UHFFFAOYSA-N

General description

5-Iodosalicylaldehyde is a salicylaldehyde derivative.

Application

5-Iodosalicylaldehyde may be used to synthesize:
  • 5-formylsalicylaldehyde
  • 5-ortho-carboranylsalicylaldehyde
  • new salen (N,N′-Bis(salicylidene)ethylenediamine) ligands that are tethered to a p-acylthio(phenylacetylene)n linker

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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An efficient and convenient synthesis of 5-formylsalicylaldehyde.
Lee SH, et al.
Synthetic Communications, 30(6), 1003-1008 (2000)
Synthesis of 5-ortho-Carboranylsalicylaldehyde and an Indolinospirobenzopyran.
Lee SH, et al.
Synthetic Communications, 39(22), 4069-4078 (2009)
Synthesis and catalytic properties of p-acylthio (phenylacetylene) n substituted chiral manganese salen complexes.
Nielsen M and Gothelf KV.
Journal of the Chemical Society. Perkin Transactions 1, 19 (2001)

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