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463736

Sigma-Aldrich

Sodium hexanitrocobaltate(III)

99.999% trace metals basis

Synonym(s):

Sodium cobaltnitrite, Sodium hexanitritocobaltate(III)

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About This Item

Linear Formula:
Na3Co(NO2)6
CAS Number:
13600-98-1
Molecular Weight:
403.94
EC Number:
237-077-7
MDL number:
MFCD00003512
UNSPSC Code:
12352302
PubChem Substance ID:
24870090

Assay

99.999% trace metals basis

form

solid

mp

220 °C (dec.) (lit.)

SMILES string

[Na+].[Na+].[Na+].[O-][N+](=O)[Co-3]([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)([N+]([O-])=O)[N+]([O-])=O

InChI

1S/Co.6NO2.3Na/c;6*2-1-3;;;/q-3;;;;;;;3*+1

InChI key

IMBXIBFCGMYSME-UHFFFAOYSA-N

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Application

Nitrosation reagent for the conversion of aromatic amines to 1,3-diaryltriazenes with excellent yield.

Signal Word

Danger

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Ox. Sol. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

5.1B - Oxidizing hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKBF6881V
MKBF7406V
MKBB7562
03222KH
06001TD

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Bogdan Stefane et al.
The Journal of organic chemistry, 62(21), 7165-7169 (2001-10-24)
Na(3)Co(NO(2))(6) has been investigated as a new reagent for the nitrosation of various substrates containing an amino functionality. Reactions took place in an aqueous solution of the reagent. The pH of the reaction mixture remained in the range 4.3-5. Thus
[Hygienic standard basis for potassium hexanitrocobaltate in the water of reservoirs].
A A Korolev
Gigiena i sanitariia, (10)(10), 72-73 (1980-10-01)
D B Green et al.
Stain technology, 65(1), 15-24 (1990-01-01)
The effect was examined of the chemical decomposition of the potassium stain sodium hexanitrocobaltate (III) (SHC), on its ability to produce stain granules of consistent size that could be used to estimate the K+ contents of stomatal guard cells. Stomata
G Krishnamoorthy et al.
Biochemistry, 41(51), 15277-15287 (2002-12-18)
Information on the structure and dynamics of condensed forms of DNA is important in understanding both natural situations such as DNA packaging and artificial systems such as gene delivery complexes. We have established the fluorescence of bisintercalator 1,1'-(4,4,8,8-tetramethyl-4,8-diazaundecamethylene)bis[4-[[3-methylbenz-1,3-oxazol-2-yl]methylidine]-1,4-dihydroquinolinium] tetraiodide (YOYO-1)
Man-Song Li et al.
British journal of pharmacology, 167(5), 1062-1075 (2012-05-23)
There is great interest in the development of potentiator drugs to increase the activity of the cystic fibrosis transmembrane conductance regulator (CFTR) in cystic fibrosis. We tested the ability of several anions to potentiate CFTR activity by a novel mechanism.
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