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234958

Sigma-Aldrich

1,4-Butanediol dimethacrylate

95%, contains 200-300 ppm MEHQ as inhibitor

Synonym(s):

BDDMA, Butanediol dimethacrylate, Tetramethylene methacrylate

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About This Item

Linear Formula:
[H2C=C(CH3)CO2CH2CH2-]2
CAS Number:
Molecular Weight:
226.27
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23

Assay

95%

form

liquid

contains

200-300 ppm MEHQ as inhibitor

refractive index

n20/D 1.456 (lit.)

bp

132-134 °C/4 mmHg (lit.)

density

1.023 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

CC(=C)C(=O)OCCCCOC(=O)C(C)=C

InChI

1S/C12H18O4/c1-9(2)11(13)15-7-5-6-8-16-12(14)10(3)4/h1,3,5-8H2,2,4H3

InChI key

XOJWAAUYNWGQAU-UHFFFAOYSA-N

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Application

  • Formulation and polymerization of foamed 1,4-BDDMA-in-water emulsions.: This study focuses on the formulation and polymerization processes of 1,4-Butanediol dimethacrylate (1,4-BDDMA) in water emulsions, showcasing its potential in creating high-performance polymer foams suitable for various industrial applications (Dabrowski et al., 2020).
  • Methacrylate-based polymer foams with controllable connectivity, pore shape, pore size and polydispersity.: The research delves into creating methacrylate-based polymer foams using 1,4-BDDMA, emphasizing its versatility in producing materials with tailored physical properties, which are crucial for biomedical and industrial uses (Dabrowski et al., 2019).
  • Double Replication of Silica Colloidal Crystal Films.: This paper discusses the replication of silica colloidal crystal films using 1,4-BDDMA, highlighting its efficacy in creating structured materials for advanced technological applications (Russell and Mallouk, 2017).
  • In-situ photocrosslinkable nanohybrid elastomer based on polybutadiene/polyhedral oligomeric silsesquioxane.: This study investigates the development of a nanohybrid elastomer using 1,4-BDDMA, focusing on its applications in medical device adhesives and high-performance polymer synthesis (Mirmohammadi et al., 2016).
  • Effects of dental methacrylates on oxygen consumption and redox status of human pulp cells.: Research highlighting the biocompatibility and potential dental applications of 1,4-BDDMA, demonstrating its impact on human pulp cells, which is critical for dental composite materials (Nocca et al., 2014).

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

10 - Combustible liquids

WGK

WGK 1

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Giuseppina Nocca et al.
European journal of oral sciences, 117(2), 175-181 (2009-03-27)
The polymerization of methacrylic monomers present in dental composite resins never reaches completion and therefore the leakage of residual monomers into the oral cavity and into biological fluids can cause local and systemic adverse effects. This work was carried out
Eeva K Viljanen et al.
Dental materials : official publication of the Academy of Dental Materials, 22(9), 845-851 (2005-12-29)
The aim of this study was to analyze the residual monomer content of photopolymerized dendritic methacrylate copolymers and particulate filler composites. Headspace-gas chromatography/mass spectrometry (HS-GC/MS) was compared with high performance liquid chromatography (HPLC). The resin mixtures consisted of a dendritic
M Roice et al.
Journal of protein chemistry, 20(1), 25-32 (2001-05-02)
Peptide segments corresponding to antibacterial esculentin-1 (1-15), (3344), (9-27), and their modified forms were synthesized on 1,4-butanediol dimethacrylate cross-linked polystyrene (PS-BDODMA) support. Hydroxymethyl and aminomethyl 2% PS-BDODMA supports were used for the synthesis. The HMPB linker was appended to the
Emma-Christin Lönnroth et al.
European journal of oral sciences, 111(5), 440-446 (2003-09-17)
Dental personnel and orthopedic surgeons are at risk when manually handling products containing methyl methacrylate (MMA). Dental products may also contain cross-linking agents such as ethylene glycol dimethacrylate (EGDMA) or 1,4-butanediol dimethacrylate (1,4-BDMA). Skin contact with monomers can cause hand
Susanna Segerström et al.
European journal of oral sciences, 113(5), 422-428 (2005-10-06)
Two matrix resins for fiber composites that remain in a fluid state during storage and handling before polymerization were evaluated. The resin mixtures, based on methyl methacrylate (MMA), were produced with two different cross-linking agent systems: 1,4-butanediol dimethacrylate and ethylene

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