23070
(1-Chloroethyl)trimethylsilane
technical, ≥90% (GC)
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About This Item
Empirical Formula (Hill Notation):
C5H13ClSi
CAS Number:
Molecular Weight:
136.70
Beilstein:
1732094
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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grade
technical
Quality Level
Assay
≥90% (GC)
form
liquid
refractive index
n20/D 1.422
bp
116 °C (lit.)
density
0.864 g/mL at 20 °C (lit.)
functional group
chloro
SMILES string
CC(Cl)[Si](C)(C)C
InChI
1S/C5H13ClSi/c1-5(6)7(2,3)4/h5H,1-4H3
InChI key
UWJVDEZZIPJQRF-UHFFFAOYSA-N
Other Notes
Treating this chlorosilane with sec-BuLi gives 1-chloro-1-trimethylsilylethyl lithium which reacts with aldehydes and ketones to form methyl ketones via an intermediate α,β-epoxysilane.; Used in an efficient synthesis of R(+)-frontalin[1][2]; The Grignard reagent is useful for many reactions[3][4][5]
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
68.0 °F
Flash Point(C)
20 °C
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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P. Magnus et al.
Journal of the Chemical Society. Chemical Communications, 297-297 (1978)
T. Hayashi et al.
The Journal of Organic Chemistry, 51, 3772-3772 (1986)
F. Cooke et al.
Organometallics, 1, 893-893 (1982)
J.A. Soderquist et al.
The Journal of Organic Chemistry, 45, 3571-3571 (1980)
S. Sato et al.
Journal of Organometallic Chemistry, 344, 71-71 (1988)
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