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291048

Sigma-Aldrich

Iodine monochloride solution

1.0 M in methylene chloride

Synonym(s):

Chloroiodide solution, Wijs solution

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About This Item

Linear Formula:
ICl
CAS Number:
7790-99-0
Molecular Weight:
162.36
Beilstein:
3587194
MDL number:
MFCD00011354
UNSPSC Code:
12352300
PubChem Substance ID:
329753313
NACRES:
NA.55

form

liquid

Quality Level

100

concentration

0.95-1.10 M (by Na2S2O3, titration)
1.0 M in methylene chloride

density

1.42 g/mL at 25 °C

SMILES string

ClI

InChI

1S/ClI/c1-2

InChI key

QZRGKCOWNLSUDK-UHFFFAOYSA-N

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Signal Word

Danger

Hazard Statements

H314,H336,H351

Hazard Classifications

Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

Target Organs

Central nervous system

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificates of Analysis (COA)

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Cation radicals as intermediates in aromatic halogenation with iodine monochloride: solvent and salt effects on the competition between chlorination and iodination.
Hubig SM, et al.
The Journal of Organic Chemistry, 59(21), 6233-6244 (1994)
Ahmed Khalil et al.
Nucleosides, nucleotides & nucleic acids, 33(12), 786-799 (2014-11-06)
The reaction of thymidine, 3-mono-, and 3,3',5'-trialkylsubstitued thymidine analogues with iodine monochloride (ICl) was investigated. Treatment with ICl resulted in rapid deglycosylation, anomerization, and isomerization of thymidine and 3-substituted thymidine analogues under various reaction conditions leading to the formation of
Polymethylbenzene complexes of iodine and iodine monochloride.
Andrews LJ and Keefer RM.
Journal of the American Chemical Society, 74(18), 4500-4503 (1952)
Ultrasonic-assisted synthesis of flavones by oxidative cyclization of 2'-hydroxychalcones using iodine monochloride.
Lahyani A and Trabelsi M.
Ultrasonics Sonochemistry, 31, 626-630 (2016)
C P Coyne et al.
American journal of veterinary research, 46(12), 2578-2581 (1985-12-01)
Two methods were analyzed for the rapid extraction of equine fibrinogen from fresh plasma, using ammonium sulfate-sodium phosphate buffer. Fibrinogen from each of these 2 methods was then radiolabeled with 125I (half-life = 60.2 days, gamma = 35 keV), using
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