701742
Copper(I) chloride - bis(lithium chloride) complex
1 M in THF
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About This Item
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form
liquid
Quality Level
reaction suitability
core: copper
reagent type: catalyst
concentration
1 M in THF
refractive index
n20/D 1.442
density
1.015 g/mL at 25 °C
SMILES string
[Li]Cl.[Li]Cl.Cl[Cu]
InChI
1S/3ClH.Cu.2Li/h3*1H;;;/q;;;3*+1/p-3
InChI key
QJRAZNXUNZEAQH-UHFFFAOYSA-K
Application
Solution used in Cu(I) transmetallation for amination reaction
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1 - Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Central nervous system, Respiratory system
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
62.6 °F
Flash Point(C)
17.0 °C
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Synthesis, 1272-1272 (2007)
General preparation of primary, secondary, and tertiary aryl amines by the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates.
Angewandte Chemie (International ed. in English), 45(46), 7838-7842 (2006-11-01)
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