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Key Documents

663042

Sigma-Aldrich

CX22

Umicore, 97%

Synonym(s):

Allylchloro[1,3-bis-(2,4,6-trimethylphenyl)imidazol-2-ylidene]palladium(II), Allyl[1,3-bis(mesityl)imidazol-2-ylidene]chloropalladium(II)

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About This Item

Empirical Formula (Hill Notation):
C24H29ClN2Pd
CAS Number:
Molecular Weight:
487.37
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

228-232 °C (dec.)

SMILES string

CC=C.Cc1cc(C)c(N2C=CN(C2[Pd]Cl)c3c(C)cc(C)cc3C)c(C)c1

InChI

1S/C21H25N2.C3H6.ClH.Pd/c1-14-9-16(3)20(17(4)10-14)22-7-8-23(13-22)21-18(5)11-15(2)12-19(21)6;1-3-2;;/h7-13H,1-6H3;3H,1H2,2H3;1H;/q;;;+1/p-1

InChI key

UZZBPJRGCGHWDS-UHFFFAOYSA-M

Legal Information

Product of Umicore

Additional information available at www.pmc.umicore.com

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

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Articles

In collaboration with Umicore AG and Co.,1 we are pleased to offer a series of robust Pd(II) and Pd(0) complexes employed as the linchpin in C–C bond forming reactions.

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