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223220

Sigma-Aldrich

Thiocarbohydrazide

98%

Synonym(s):

Thiocarbonyldihydrazide

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About This Item

Linear Formula:
(NH2NH)2CS
CAS Number:
2231-57-4
Molecular Weight:
106.15
Beilstein:
506657
EC Number:
218-769-8
MDL number:
MFCD00007616
UNSPSC Code:
12352100
eCl@ss:
39093513
PubChem Substance ID:
24853371
NACRES:
NA.22
Pricing and availability is not currently available.

Assay

98%

form

solid

mp

171-174 °C (dec.) (lit.)

functional group

amine
hydrazine
thiourea

SMILES string

NNC(=S)NN

InChI

1S/CH6N4S/c2-4-1(6)5-3/h2-3H2,(H2,4,5,6)

InChI key

LJTFFORYSFGNCT-UHFFFAOYSA-N

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Application


  • Review of transition metal complexes with thiocarbohydrazides: This comprehensive review discusses the coordination chemistry of thiocarbohydrazides with various metals, highlighting their relevance in the synthesis of complex metal compounds used in catalysis and pharmaceutical research (Aly et al., 2023).

  • Pd-doped nanocomposites for organometallic catalysis: Thiocarbohydrazide was employed in the fabrication of Pd-doped SBA-15 nanocomposites, applied as catalysts in the synthesis of organometallic compounds, showcasing its utility as a catalyst support material (Kalhor and Dadras, 2021).

Pictograms

Skull and crossbones
GHS06

Signal Word

Danger

Hazard Statements

H300 + H330,H311

Hazard Classifications

Acute Tox. 2 Oral

Storage Class Code

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
STBL2996
STBK9373
STBK3832
STBJ5587
STBH8445

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Kamaleddin Haj Mohammad Ebrahim Tehrani et al.
Iranian journal of pharmaceutical research : IJPR, 12(2), 331-346 (2013-11-20)
In this work, we reported the synthesis and evaluation of antimycobacterial and antifungal activity of a series of thiocarbohydrazone derivatives which are thiacetazone congeners. The target compounds were synthesized in superior yields by reacting thiocarbohydrazide with different aromatic aldehydes and
D Levanon et al.
The Histochemical journal, 31(1), 71-73 (1999-07-16)
Samples from seven sectors of the rabbit knee articular cartilage were shaved and prepared for the scanning electron microscope using either tannic acid, thiocarbohydrazide or nothing (control). Surface morphology was found to be more typical to a given sector and
D P Singh et al.
Journal of enzyme inhibition and medicinal chemistry, 22(2), 177-182 (2007-05-24)
A novel series of complexes of the type [M(TML)X2]; where TML is Tetradentate Macrocyclic Ligand; M = Co(II), Ni(II), Cu(II), Zn(II)or Cd(II); X = Cl-, CH3COO- or NO3- have been synthesized by template condensation of glyoxal and thiocarbohydrazide in the
Debabrata Maity et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 17(40), 11152-11161 (2011-09-02)
We present novel Schiff base ligands julolidine-carbonohydrazone 1 and julolidine-thiocarbonohydrazone 2 for selective detection of Cu(2+) in aqueous medium. The planar julolidine-based ligands can sense Cu(2+) colorimetrically with characteristic absorbance in the near-infrared (NIR, 700-1000 nm) region. Employing molecular probes
M Goldberg et al.
European journal of oral sciences, 104(3), 269-277 (1996-06-01)
The appearance of the junction between predentin and dentin of rat incisors was investigated after chemical fixation (aldehyde), physical fixation (high pressure freezing and freeze substitution) and by histochemistry. Physical fixation revealed a 1-2 micron wide intermediary zone, in which
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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
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      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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