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About This Item
Linear Formula:
CH3CSSCH2CH3
CAS Number:
Molecular Weight:
120.24
Beilstein:
1737711
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Assay
98%
form
liquid
refractive index
n20/D 1.568 (lit.)
bp
61 °C/23 mmHg (lit.)
density
1.048 g/mL at 25 °C (lit.)
functional group
thioether
SMILES string
CCSC(C)=S
InChI
1S/C4H8S2/c1-3-6-4(2)5/h3H2,1-2H3
InChI key
KCOPWUJJPSTRIZ-UHFFFAOYSA-N
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General description
Ethyl dithioacetate is an alkyl dithioester. It reacts with 5,6-diamino-1,3-dimethyluracil to yield the purine derivative. Raman spectra of ethyl dithioacetate has been recorded as a function of temperature in the liquid phase and in the solid phase at low temperature.
Application
Ethyl dithioacetate may be used in the preparation of N-thioacetylamino acids.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
3 - Flammable liquids
WGK
WGK 3
Flash Point(F)
114.8 °F - closed cup
Flash Point(C)
46 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Thioacetylation method of protein sequencing: Gas chromatography/Ion trap mass spectrometric detection of 5-acetoxy-2-methylthiazoles.
Stolowitz ML, et al.
Journal of Protein Chemistry, 11(4), 360-361 (1992)
2-?-d-ribofuranosylbenzoxazole from 2, 5-anhydro-d-allonoimidate, and 1, 3-dimethyl-8-?-d-ribofuranosylxanthine from 2, 5-anhydro-d-allono-thioimidates and-dithioates.
El Khadem HS and Kawai J.
Carbohydrate Research, 153(2), 271-283 (1986)
Rotational isomers of ethyl dithioacetate and ethyl thionoacetate: A Raman study.
Verma AL, et al.
Journal of Raman Spectroscopy, 11(5), 390-392 (1981)
Renwu Li et al.
Bioorganic & medicinal chemistry, 28(7), 115356-115356 (2020-02-19)
Past few years have seen an active pursuit of the inhibitors for the deacylation catalyzed by the seven human sirtuins (i.e. SIRT1-7) as valuable chemical biological/pharmacological probes of this enzymatic deacylation and lead compounds for developing novel therapeutics for human
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