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230286

Sigma-Aldrich

Phosphonitrilic chloride trimer

99%

Synonym(s):

1,3,5,2,4,6-Triazatriphosphorine-2,2,4,4,6,6-hexachloride, 1,3,5-Triaza-2,4,6-triphosphorin-2,2,4,4,6,6-hexachloride, Hexachlorocyclotriphosphazene

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About This Item

Linear Formula:
(NPCl2)3
CAS Number:
940-71-6
Molecular Weight:
347.66
EC Number:
213-376-8
MDL number:
MFCD00006474
UNSPSC Code:
12162002
PubChem Substance ID:
24853791
NACRES:
NA.23

Assay

99%

form

solid

mp

112-115 °C (lit.)

density

1.98 g/mL at 25 °C (lit.)

SMILES string

Clp1(Cl)np(Cl)(Cl)np(Cl)(Cl)n1

InChI

1S/Cl6N3P3/c1-10(2)7-11(3,4)9-12(5,6)8-10

InChI key

UBIJTWDKTYCPMQ-UHFFFAOYSA-N

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Application

Reagent for the synthesis of ″dandelion″ (spherical) dendrimers. Ring-opening polymerization, ligand and/or ligand precursor for transition metals, and the study of P-Cl bond substitution reactions are among the interesting uses for this product.

Pictograms

Corrosion
GHS05

Signal Word

Danger

Hazard Statements

H314

Hazard Classifications

Skin Corr. 1B

Supplementary Hazards

EUH014

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Studies on the reaction of hexachlorocyclotriphosphazene and 2-hydroxyethyl methacrylate and on the physical properties of its polymer.
M Anzai et al.
The Journal of Nihon University School of Dentistry, 26(2), 109-118 (1984-06-01)
Ji-Yeon Seong et al.
International journal of pharmaceutics, 314(1), 90-96 (2006-03-22)
Biocompatible and thermosensitive poly(organophosphazenes) with a lower critical solution temperature (LCST) below body temperature have been designed with the aim for the local delivery of peptide and protein drugs. These polymers could be synthesized by introducing short chain tri- or
Hiroyoshi Kawakami et al.
Artificial organs, 26(10), 883-890 (2002-09-26)
We investigated biodegradation and biocompatibility of poly(organophosphazenes). We prepared poly(organophosphazenes) having different side chain groups. The blood compatibility of poly(organophosphazenes) containing fluorinated side groups, poly(bis[trifluoroethoxy]phosphazene) (PbFP) and poly([trifluoroethoxy][ethyl glycinate]phosphazene) (PFGP), without heparinization were evaluated in vitro. The deformation and aggregation
David K Y Lee et al.
Dalton transactions (Cambridge, England : 2003), 39(22), 5341-5348 (2010-05-05)
Two novel cyclic phosphazenes with asymmetric spiro rings were synthesized via reactions of hexachlorocyclotriphosphazene with chiral amino alcohol residues. The reactions showed preferential formation of the cis isomer possibly due to the delocalization of the lone pair electrons of the
Wajdi M Zoghaib et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 105, 446-455 (2013-01-26)
The Raman (1400-100 cm(-1)) and infrared (4000-400 cm(-1)) of solid hexachlorocyclotriphosphazene, P(3)N(3)Cl(6) (HCCTP) were recorded. The conformational energies were calculated using MP2 and DFT (B3LYP and B3PW91) methods utilizing a variety of basis sets up to 6-311+G(d). On the basis
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