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139572

Sigma-Aldrich

2,4-Dichlorobenzoic acid

98%

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About This Item

Linear Formula:
Cl2C6H3CO2H
CAS Number:
50-84-0
Molecular Weight:
191.01
Beilstein:
1868192
EC Number:
200-067-8
MDL number:
MFCD00002414
UNSPSC Code:
12352100
PubChem Substance ID:
24848423
NACRES:
NA.22

Assay

98%

mp

157-160 °C (lit.)

solubility

ethanol: soluble 1 g/10 mL, clear, colorless

SMILES string

OC(=O)c1ccc(Cl)cc1Cl

InChI

1S/C7H4Cl2O2/c8-4-1-2-5(7(10)11)6(9)3-4/h1-3H,(H,10,11)

InChI key

ATCRIUVQKHMXSH-UHFFFAOYSA-N

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General description

2,4-Dichlorobenzoic acid is the degradation product of chlorfenvinphos in water treated by photo-fenton driven by solar irradiation.

Application

2,4-Dichlorobenzoic acid was used in solid-phase extraction and gas chromatographic determination of polar acidic herbicides in surface water. It was used as reagent during the synthesis of pyrimido[2′,1′:2,3]thiazolo[4,5-b]quinoxaline derivatives. It was used as starting reagent during the synthesis of 1-(substituted)-1,4-dihydro-6-nitro-4-oxo-7-(sub-secondary amino)-quinoline-3-carboxylic acids.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H315,H319,H335

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Gas chromatographic determination of acid herbicides in surface water samples with electron-capture detection and mass spectrometric confirmation.
Vink M and Van der Poll JM.
Journal of Chromatography A, 733(1), 361-366 (1996)
Sunday A Adebusoye et al.
Bioresource technology, 102(3), 3041-3048 (2010-11-16)
Multiple bacterial strains with CBA metabolic properties were isolated using a simple selective strategy. Phylogenetic analysis of the 16S rRNA gene sequences grouped them into two main clusters consisting of four bacterial phyla and belonging to 17 genera. Whereas growth
G M Zaitsev et al.
FEMS microbiology letters, 65(2), 171-176 (1991-06-15)
The strains of Arthrobacter globiformis KZT1, Corynebacterium sepedonicum KZ4 and Pseudomonas cepacia KZ2 capable of early dehalogenation and complete oxidation of 4-chloro-, 2,4-dichloro-and 2-chlorobenzoic acids, respectively, have been analyzed for the origin of the genetic control of degradation. The occurrence
Anthony D Wright et al.
Chemosphere, 65(4), 604-608 (2006-03-24)
The toxic effects of several species of fresh water cyanobacteria, notably Microcystis species and associated toxins, the microcystins, Anabaena species (anatoxin), Nodularia sp. (nodularin), and Cylindrospermopsis raciborskii (cylindrospermopsin), are well known. Little, however, is known about the effects of secondary
Daniel J Repeta et al.
Environmental science & technology, 38(20), 5373-5378 (2004-11-17)
Chromophoric or colored dissolved organic matter (CDOM) is one of the principal light adsorbing components of seawater, particularly in the ultraviolet, where it attenuates over 90% of downwelling ultraviolet radiation. In highly productive coastal regions and throughout most of the
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