115819
2,2′-Biphenol
99%
Synonym(s):
2,2′-Biphenyldiol, 2,2′-Dihydroxybiphenyl, 2,2′-Diphenol
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About This Item
Linear Formula:
HOC6H4C6H4OH
CAS Number:
Molecular Weight:
186.21
Beilstein:
1638363
EC Number:
MDL number:
UNSPSC Code:
12162002
PubChem Substance ID:
NACRES:
NA.23
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Quality Level
Assay
99%
form
solid
bp
315 °C (lit.)
mp
108-110 °C (lit.)
SMILES string
Oc1ccccc1-c2ccccc2O
InChI
1S/C12H10O2/c13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)14/h1-8,13-14H
InChI key
IMHDGJOMLMDPJN-UHFFFAOYSA-N
Related Categories
Storage Class Code
11 - Combustible Solids
WGK
WGK 2
Flash Point(F)
309.2 °F - closed cup - (External MSDS)
Flash Point(C)
154 °C - closed cup - (External MSDS)
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Atsushi Kuwahara et al.
The Journal of organic chemistry, 70(2), 413-419 (2005-01-18)
The double N-arylation of primary amines with 2,2'-biphenylylene ditriflates was investigated for the synthesis of multisubstituted carbazoles. Palladium complexes supported by 2-dicyclohexylphosphino-2'-methylbiphenyl or Xantphos [4,5-bis(diphenylphosphino)-9,9-dimethylxanthene] were found to be efficient catalysts for the reaction. The catalysts allow the use of
V V Subrahmanyam et al.
Xenobiotica; the fate of foreign compounds in biological systems, 20(12), 1369-1378 (1990-12-01)
1. 14C-Phenol was metabolized by rat bone marrow homogenate and H2O2. The homogenate catalyst, however, was inactivated by preincubation with H2O2, presumably due to inactivation of the enzyme(s) involved in phenol metabolism. 2. The majority of the metabolized 14C-phenol was
Zwe-Ling Kong et al.
Bioorganic & medicinal chemistry letters, 15(1), 163-166 (2004-12-08)
The neolignans, magnolol 1 and honokiol 2 have been reported to inhibit the growth of several tumor cell lines in vitro and in vivo. The chemical structure of magnolol and honokiol consists of biphenyl skeleton with phenolic and allylic functionalities.
Bernd Schmidt et al.
The Journal of organic chemistry, 78(17), 8680-8688 (2013-08-01)
User-friendly protocols for the protecting group-free synthesis of 2,2'-biphenols via Suzuki-Miyaura coupling of o-halophenols and o-boronophenol are presented. The reactions proceed in water in the presence of simple additives such as K2CO3, KOH, KF, or TBAF and with commercially available
Sierra Rayne et al.
Photochemical & photobiological sciences : Official journal of the European Photochemistry Association and the European Society for Photobiology, 4(11), 876-886 (2005-10-28)
Photochemical studies on a range of model dibenzo[1,4]dioxins were performed in aqueous and organic solutions. The compounds were found to undergo a photochemically initiated aryl-ether bond homolysis that yields reactive 2-spiro-6'-cyclohexa-2',4'-dien-1'-one and subsequent 2,2'-biphenylquinone intermediates. Under steady-state irradiation, the 2,2'-biphenylquinones
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