695076

Ácido fórmico

ACS reagent, ≥96%

• Fórmula lineal: HCOOH
• Número de CAS: 64-18-6
• Peso molecular: 46.03
• Beilstein/REAXYS Number: 1209246
• EC Number: 200-579-1
• MDL number: MFCD00003297
• UNSPSC Code: 12352106
• PubChem Substance ID: 329761713
• NACRES: NA.21

Propiedades

• grade: ACS reagent
• Quality Level: 200
• vapor density: 1.6 (vs air)
• vapor pressure: 44.8 mmHg ( 20 °C)
• assay: ≥96%
• form: liquid
• autoignition temp.: 1004 °F
• expl. lim.: 57 %
• refractive index: n20/D 1.370 (lit.)
• pH: 2.2 (20 °C, 2.2 g/L)
• bp: 100-101 °C (lit.)
• mp: 8.2-8.4 °C (lit.)
• solubility: water: miscible
• density: 1.22 g/mL at 25 °C (lit.)
• anion traces: chloride (Cl^-): ≤0.001%; sulfate (SO₄^2-): ≤0.003%; sulfite (SO₃^2-): passes test
• cation traces: Fe: ≤0.001%; NH₄⁺: ≤0.005%; heavy metals (as Pb): ≤0.001%
• application(s): sample preparation
• SMILES string: OC=O
• InChI: 1S/CH2O2/c2-1-3/h1H,(H,2,3)
• InChI key: BDAGIHXWWSANSR-UHFFFAOYSA-N

Descripción

General description

Formic acid is a simple carboxylic acid produced by the hydrolysis of methyl formate or formamide or from its salts. It is primarily used in dyeing, textile, leather, rubber, chemical, and pharmaceutical industries.

Application

Formic acid can be used as a reagent in the:

• Co-N_x-catalyzed one-pot reductive amination of carbonyl compounds with nitro compounds to synthesize secondary amines.
• Photoreduction of polycyclic and heterocyclic nitro arenes to corresponding amines.
• Pd-catalyzed chemoselective hydrogenation of olefins to saturated hydrocarbons.

Información de seguridad

• pictograms: GHS02,GHS06,GHS05
• signalword: Danger
• hcodes: H226,H302,H314,H331
• pcodes: P210 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
• supp_hazards: EUH071
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: 121.1 °F - closed cup
• flash_point_c: 49.5 °C - closed cup