366374

Zinc chloride solution

0.5 M in THF

• Fórmula lineal: ZnCl₂
• Número de CAS: 7646-85-7
• Peso molecular: 136.30
• MDL number: MFCD00011295
• UNSPSC Code: 12352302
• PubChem Substance ID: 329755428
• NACRES: NA.55

Propiedades

• form: liquid
• Quality Level: 100
• concentration: 0.5 M in THF; 470-600 mmol/L (silver nitrate titration)
• density: 0.948 g/mL at 25 °C
• SMILES string: Cl[Zn]Cl
• InChI: 1S/2ClH.Zn/h2*1H;/q;;+2/p-2
• InChI key: JIAARYAFYJHUJI-UHFFFAOYSA-L

Descripción

General description

Zinc chloride solution is a colorless liquid that contains zinc chloride dissolved in THF. Its synthesis has been reported.

Application

Zinc chloride solution was used in the synthesis of the ferrocenylarenes.
It may be used for the in situ generation of organozincate reagents by reacting with Grignard compounds and also to catalyze chloromethylation of resins for solid phase peptide synthesis.

Información de seguridad

• pictograms: GHS02,GHS08,GHS05,GHS07,GHS09
• signalword: Danger
• hcodes: H225,H302,H314,H335,H336,H351,H411
• pcodes: P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• target_organs: Central nervous system, Respiratory system
• supp_hazards: EUH019
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: -4.0 °F - closed cup
• flash_point_c: -20 °C - closed cup