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Merck

GF75301668

Samarium

foil, not light tested, 50x50mm, thickness 0.025mm, as rolled, 99%

Sinónimos:

Samarium, SM000200

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About This Item

Fórmula empírica (notación de Hill):
Sm
Número de CAS:
Peso molecular:
150.36
MDL number:
UNSPSC Code:
12141612
PubChem Substance ID:
NACRES:
NA.23

assay

99%

form

foil

manufacturer/tradename

Goodfellow 753-016-68

resistivity

91.4 μΩ-cm, 0°C

size × thickness

50 x 50 mm × 0.025 mm

bp

1794 °C (lit.)

mp

1074 °C (lit.)

density

7.47 g/mL at 25 °C (lit.)

SMILES string

[Sm]

InChI

1S/Sm

InChI key

KZUNJOHGWZRPMI-UHFFFAOYSA-N

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General description

For updated SDS information please visit www.goodfellow.com.

Legal Information

Product of Goodfellow

pictograms

Flame

signalword

Warning

hcodes

Hazard Classifications

Water-react 3

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Lot/Batch Number

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Y Kamochi et al.
Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 120(3), 245-255 (2000-03-21)
This review deals with the rapid reduction of a variety of organic functionalities, including a new selective reduction of carboxylic acid, with samarium diiodide in the presence of additives under mild conditions. The single electron donor ability of samarium diiodide
Jose M Concellón et al.
Chemical Society reviews, 33(9), 599-609 (2004-12-14)
The development of methodologies for the formation of carbon-carbon double bonds could be considered one of the most important challenges in organic synthesis. To this end, beta-elimination reactions in 1,2-difunctionalised substrates have been one of the most important means of
A N Serafini
Cancer, 88(12 Suppl), 2934-2939 (2000-07-18)
In patients with bone pain due to metastatic disease, intravenous systemic radioisotope therapy may be a useful adjunct to other methods for palliating pain. Various studies have been performed utilizing a short-lived radioisotope conjugated to a tetraphosphonate (samarium 153 lexidronam)
K C Nicolaou et al.
Angewandte Chemie (International ed. in English), 48(39), 7140-7165 (2009-08-29)
Introduced by Henri Kagan more than three decades ago, samarium diiodide (SmI(2)) has found increasing application in chemical synthesis. This single-electron reducing agent has been particularly useful in C-C bond formations, including those found in total synthesis endeavors. This Review
José M Concellón et al.
Chemical Society reviews, 39(11), 4103-4113 (2010-08-05)
Samarium metal and samarium diiodide have become important tools as selective cyclopropanating agents in organic synthesis due to their high chemo- and stereoselectivity. Therefore, Sm and SmI(2) are the ideal reagents to prepare cyclopropane derivatives. This tutorial review highlights C-C

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