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Merck
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Key Documents

932434

Sigma-Aldrich

TcTa

≥99% (HPLC)

Sinónimos:

4,4′,4′′-Tri-9-carbazolyltriphenylamine, 4,4′,4′′-tris(carbazol-9-yl)-triphenylamine, 4,4′,4-Tris(carbazol-9-yl)triphenylamine, Tris(4-(9H-carbazol-9-yl)phenyl)amine

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About This Item

Fórmula empírica (notación de Hill):
C54H36N4
Número de CAS:
139092-78-7
Peso molecular:
740.89
MDL number:
MFCD03093250
UNSPSC Code:
41106305
NACRES:
NA.23

grade

sublimed grade

Quality Level

100

description

μh ≈ 3.0 x 10-4 cm2 V−1 s−1
μe ≈ 1.0 x 10-8 cm2 V−1 s−1

assay

≥99% (HPLC)

loss

0.5% TGA, > 410 °C (weight loss)

mp

299 °C

solubility

THF: soluble
chloroform: soluble
dichloromethane: soluble

λmax

293 nm±5 nm in THF
326 nm±5 nm in THF

fluorescence

λem 385 nm±10 nm in THF

orbital energy

HOMO 5.8 eV 
LUMO 2.4 eV 

SMILES string

c1ccc2c(c1)n(-c3ccc(cc3)N(c4ccc(cc4)-n5c6ccccc6c7ccccc57)c8ccc(cc8)-n9c%10ccccc%10c%11ccccc9%11)c%12ccccc2%12

InChI

1S/C54H36N4/c1-7-19-49-43(13-1)44-14-2-8-20-50(44)56(49)40-31-25-37(26-32-40)55(38-27-33-41(34-28-38)57-51-21-9-3-15-45(51)46-16-4-10-22-52(46)57)39-29-35-42(36-30-39)58-53-23-11-5-17-47(53)48-18-6-12-24-54(48)58/h1-36H

InChI key

AWXGSYPUMWKTBR-UHFFFAOYSA-N

Categorías relacionadas

Application

It′s a star-shaped carbazole hole-transporting material popularly used in OLEDs as solution-processable fluorescent emitting host, or as electron-blocking layer for quantum-dot light-emitting diodes (QD-LEDs).
TCTA is widely used as a hole transport material in OLED and organic photovoltaic (OPV) devices. It possesses excellent hole injection and transport properties, helping to efficiently transport positive charges (holes) from the anode to the emitting layer.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCW6140
MKCT1310

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Visite la Librería de documentos

Benjamin T Feleki et al.
ACS applied energy materials, 4(4), 3033-3043 (2021-06-01)
Parasitic optical absorption is one of the root causes of the moderate efficiency of metal halide perovskite solar cells (PSCs) with an opaque substrate configuration. Here, we investigate the reduction of these optical losses by using thin (7-10 nm), undoped
Chang-Ki Moon et al.
Advanced materials (Deerfield Beach, Fla.), 29(17) (2017-03-02)
Inter- and intramolecular charge-transfer processes are combined using an exciplex-forming host and a thermally activated delayed fluorescent dopant, for fabricating efficient fluorescent organic light-emitting diodes along with the reduced efficiency roll-off at high current densities. Extra conversion on the host
Lead-Free Halide Light-Emitting Diodes with External Quantum Efficiency Exceeding 7% Using Host?Dopant Strategy
Seo Gijun, et al.
ACS Energy Letters, 6, 2584?2593-2584?2593 (2021)
Boosting Triplet Harvest by Reducing Nonradiative Transition of Exciplex toward Fluorescent Organic Light-Emitting Diodes with 100% Internal Quantum Efficiency
Kim, Kwon-Hyeon, et al.
Chemistry of Materials, 28, 1936-1941 (2016)

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