86262

2-Methyl-2-butene

≥95.0% (GC)

• Sinónimos: β-Isoamylene, Amylene
• Fórmula lineal: CH₃CH=C(CH₃)₂
• Número de CAS: 513-35-9
• Peso molecular: 70.13
• Beilstein/REAXYS Number: 1361353
• EC Number: 208-156-3
• MDL number: MFCD00009276
• UNSPSC Code: 12352100
• PubChem Substance ID: 57653087
• NACRES: NA.22

Propiedades

• vapor density: 2.4 (vs air)
• Quality Level: 100
• assay: ≥95.0% (GC)
• form: liquid
• expl. lim.: 8.7 %
• refractive index: n20/D 1.385 (lit.); n20/D 1.388
• bp: 35-38 °C (lit.)
• mp: −134 °C (lit.)
• density: 0.662 g/mL at 25 °C (lit.)
• SMILES string: C\C=C(\C)C
• InChI: 1S/C5H10/c1-4-5(2)3/h4H,1-3H3
• InChI key: BKOOMYPCSUNDGP-UHFFFAOYSA-N

Descripción

General description

2-Methyl-2-butene is a trisubstituted olefin. It acts as guest and forms stable solid host-guest complexes with self-assembled benzophenone bis-urea macrocycles. The impact of active chlorine on photo-oxidation of 2-methyl-2-butene was studied. Photosensitized oxidation of 2-methyl-2-butene adsorbed on internal framework of Na-ZSM-5 zeolite was studied. Gas-phase reaction of 2-methyl-2-butene with ozone has been investigated. Kinetics of liquid-phase alkylation of 3-methylthiophene with 2-methyl-2-butene on supported phosphoric acid has been reported.

2-methyl-2-butene undergoes ultraviolet irradiation, leading to the formation of trimethylene oxides.

Application

2-Methyl-2-butene may be employed as precursor for peroxyacetyl nitrate for the calibration purposes.

Información de seguridad

• pictograms: GHS02,GHS08,GHS07,GHS09
• signalword: Danger
• hcodes: H224,H302,H304,H336,H341,H411
• pcodes: P210 - P233 - P273 - P301 + P310 - P331 - P403 + P233
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Chronic 2 - Asp. Tox. 1 - Flam. Liq. 1 - Muta. 2 - STOT SE 3
• target_organs: Central nervous system
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: -4.0 °F
• flash_point_c: -20 °C
• ppe: Eyeshields, Faceshields, Gloves