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677922

Sigma-Aldrich

Bis(trifluoromethanesulfonyl)imidate(triphenylphosphine)gold (I) toluene adduct

Sinónimos:

[Bis(trifluoromethanesulfonyl)imidate](PPh3)gold(I) (2:1) toluene adduct

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About This Item

Fórmula lineal:
(C20H15AuF6NO4PS2) 2 · C7H8
Peso molecular:
1570.93
MDL number:
MFCD09038445
UNSPSC Code:
12161600
PubChem Substance ID:
24885406
NACRES:
NA.22

form

solid

Quality Level

100

reaction suitability

core: gold
reagent type: catalyst

SMILES string

[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.[Au]N(S(=O)(C(F)(F)F)=O)S(=O)(C(F)(F)F)=O.CC1=CC=CC=C1.P(C2=CC=CC=C2)(C3=CC=CC=C3)C4=CC=CC=C4.P(C5=CC=CC=C5)(C6=CC=CC=C6)C7=CC=CC=C7

InChI

1S/2C18H15P.C7H8.2C2F6NO4S2.2Au/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-7-5-3-2-4-6-7;2*3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;;/h2*1-15H;2-6H,1H3;;;;/q;;;2*-1;2*+1

InChI key

SIVCTOVPPFSWEF-UHFFFAOYSA-N

Application

Gold Catalysts — 21st Century ′Gold Rush′
[Bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I) (2:1) toluene adduct can be used as a catalyst in the 1,3-isomerisation of propargylic alcohols to enones via Meyer-Schuster rearrangement.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificados de análisis (COA)

Lot/Batch Number
MKCT3507
MKCQ9228
MKCP3379
MKCN1554
MKCL4954

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Research spans transition-metal catalysis, boron chemistry, organocatalysis, multicomponent reactions, and sustainable methods.

Sheppard Group – Prof. Product Portal

Research spans transition-metal catalysis, boron chemistry, organocatalysis, multicomponent reactions, and sustainable methods.

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