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Merck

674753

Sigma-Aldrich

Acetilacetonato de aluminio

purified by sublimation, 99.999% trace metals basis

Sinónimos:

2,4-Pentanodionato de aluminio, Al(acac)3

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About This Item

Fórmula lineal:
Al(C5H7O2)3
Número de CAS:
Peso molecular:
324.31
Beilstein/REAXYS Number:
4157942
EC Number:
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

99.999% trace metals basis

form

powder
solid

purified by

sublimation

reaction suitability

core: aluminum

bp

315 °C (lit.)

mp

190-193 °C (lit.)

SMILES string

CC(=O)\C=C(\C)O[Al](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O

InChI

1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-;

InChI key

KILURZWTCGSYRE-LNTINUHCSA-K

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pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 2 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

244.4 °F

flash_point_c

118 °C

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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B Corain et al.
Biomedical and environmental sciences : BES, 1(3), 283-287 (1988-10-01)
Aluminum acetylacetonate was administered to New Zealand white rabbits as liposome preparations and was found to distribute approximately 1:1 between water and phosphatidylcholine dipalmitoyl vesicles. Biochemical monitoring proved that after 2 weeks of daily injection of 40 micrograms of Al(III)
M Favarato et al.
Brain research, 569(2), 330-335 (1992-01-13)
To determine the influence of the metal coordination sphere on the permeability of the blood-brain barrier (BBB), rats were injected intraperitoneally with aluminum lactate (Al(lact)3), aluminum acetylacetonate (Al(acac)3), aluminum maltolate (Al(malt)3) at pH 7.5, or with physiological saline. Two h
T Ohyashiki et al.
Biochimica et biophysica acta, 1389(2), 141-149 (1998-02-14)
In the present study, the efficacy of a lipophilic Al complex, aluminum acetylacetonate, as a stimulator of Fe2+-initiated lipid peroxidation in phospholipid liposomes was examined, and results were compared with those from the liposomes treated with AlCl3. The extent of
P Zatta et al.
Toxicology letters, 45(1), 15-21 (1989-01-01)
Tris acetylacetonate aluminium(III) (Al(acac)3), dissolved in water, is effective in producing osmotic fragility in suspended erythrocytes in the concentration range of 0.034-0.34 mmol/l. Water solutions of Tris maltolate aluminium(III) (Al(malt)3) and aluminium lactate (Al(lac)3) are also effective but the dose-response
John W Logan et al.
Solid state nuclear magnetic resonance, 22(2-3), 97-109 (2002-12-10)
Additional experimental evidence of rotary resonance effects for multiple-quantum coherence conversion in a spin-5/2 system is presented. Two-dimensional plots of the relative efficiency of MQ excitation and conversion are given as a function of radio frequency (rf) amplitude and pulse

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