499307
Phenethylzinc bromide solution
0.5 M in THF
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About This Item
Fórmula lineal:
C6H5CH2CH2ZnBr
Número de CAS:
Peso molecular:
250.45
MDL number:
UNSPSC Code:
12352103
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
concentration
0.5 M in THF
bp
65 °C
density
0.965 g/mL at 25 °C
functional group
phenyl
storage temp.
2-8°C
SMILES string
Br[Zn]CCc1ccccc1
InChI
1S/C8H9.BrH.Zn/c1-2-8-6-4-3-5-7-8;;/h3-7H,1-2H2;1H;/q;;+1/p-1
InChI key
SEXSOTWHLBYVNF-UHFFFAOYSA-M
Application
Phenethylzinc bromide can be used as a reagent:
- In the transition metal-catalyzed Negishi cross-coupling reaction to prepare aryl or heteroaryl derivatives by reacting with organic halides or triflates via carbon-carbon bond formation.
- To prepare (4-phenyl-1-butyn-1-yl)benzene by reacting with phenylacetylene via palladium-catalyzed cross-coupling reaction.
- To synthesize benzyl substituted thienopyrimidine derivatives.
Legal Information
Product of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
Rieke is a registered trademark of Rieke Metals, Inc.
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Irrit. 2 - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk_germany
WGK 3
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
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