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Merck

449903

Sigma-Aldrich

Lithium fluoride

greener alternative

≥99.99% trace metals basis

Sinónimos:

Fluorolithium

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About This Item

Fórmula lineal:
LiF
Número de CAS:
Peso molecular:
25.94
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

grade

anhydrous

Quality Level

assay

≥99.99% trace metals basis

form

powder and chunks

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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impurities

≤100.0 ppm Trace Metal Analysis

bp

1673 °C/1 atm (lit.)

mp

845 °C (lit.)

solubility

aqueous acid: slightly soluble(lit.)

density

2.64 g/mL at 25 °C (lit.)

greener alternative category

SMILES string

[Li+].[F-]

InChI

1S/FH.Li/h1H;/q;+1/p-1

InChI key

PQXKHYXIUOZZFA-UHFFFAOYSA-M

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General description

Lithium fluoride is a white crystalline solid with a high melting point. It is widely applied in the field of rechargeable batteries, storage devices, and thermoluminescent materials. LiF is also used as a coupling layer in OLED or PLED devices to enhance electron injection. On the other hand, it is preferred for optical applications due to its wide band gap, which allows it to transmit light efficiently.
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Application

Lithium fluoride can be used:
  • As an additive to fabricate SiO@C/graphite composite anode materials for Li-ion batteries. LiF stabilizes solid electrolyte interphase (SEI) and enhances initial coulombic efficiency.
  • As a critical component in SEI for stabilizing the SEI layer and improving the cycling efficiency of Li metal batteries.
  • To fabricate electron contacts for high-efficiency n-type crystalline silicon solar cells.
  • To prepare solid-state light sources for radiation imaging detectors.
  • To synthesize highly crystalline MXene for asymmetric supercapacitor applications. And also, lightweight, flexible, and hydrophobic MXene foam with reasonable strength, high electrical conductivity, and an outstanding EMI-shielding performance.
  • As an electron-injection layer to fabricate ITO/PEDOT:PSS/perovskite/B3PYMPM/ LiF/Al OLED device with a quantum efficiency of 20%.

pictograms

Skull and crossbones

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

supp_hazards

Storage Class

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Visite la Librería de documentos

Improving the electrochemical properties of a SiO@C/graphite composite anode for high-energy lithium-ion batteries by adding lithium fluoride
Mao Xia, et al.
Applied Surface Science, 480, 410-418 (2019)
A safe etching route to synthesize highly crystalline Nb2CTx MXene for high performance asymmetric supercapacitor applications
Junpeng Xiao, et al.
Electrochimica Acta, 337, 135803-135803 (2020)
Radiat. Prot. Dosim., 66, 101-101 (1996)
Photoluminescence of colour centres in lithium fluoride thin films: from solid-state miniaturised light sources to novel radiation imaging detectors
R M Montereali, et al.
Journal of Luminescence, 170, 761-769 (2016)
Perovskite light-emitting diodes with external quantum efficiency exceeding 20 per cent
Kebin Lin, et al.
Nature, 562, 245-248 (2018)

Artículos

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

Professor Gogotsi and Dr. Shuck introduce MXenes: a promising family of two-dimensional materials with a unique combination of high conductivity, hydrophilicity, and extensive tunability.

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