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379387

Sigma-Aldrich

Dithiooxamide

97%

Sinónimos:

Dithiooxalic diamide, Rubeanic acid

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About This Item

Fórmula lineal:
NH2CSCSNH2
Número de CAS:
79-40-3
Peso molecular:
120.20
Beilstein/REAXYS Number:
605577
EC Number:
201-203-9
MDL number:
MFCD00004941
UNSPSC Code:
12352100
PubChem Substance ID:
24863627
NACRES:
NA.22

Quality Level

100

assay

97%

form

powder

mp

≥300 °C (lit.)

solubility

ethanol: soluble 40 mg/10 mL, clear, red

functional group

amine

SMILES string

NC(=S)C(N)=S

InChI

1S/C2H4N2S2/c3-1(5)2(4)6/h(H2,3,5)(H2,4,6)

InChI key

OAEGRYMCJYIXQT-UHFFFAOYSA-N

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General description

Dithiooxamide is reported to form complexes with Ni(II).

Application

Dithiooxamide may be used in the following studies:
  • Synthesis of thiazolothiazole-linked porous organic polymers under solvothermal conditions.
  • As modifier to prepare the modified glassy carbon electrode, used to investigate the electrochemical properties of quercetin, an important flavonoid derivative.
  • Synthesis of new chelating resin of dithiooxamide (rubeanic acid)-formaldehyde (DTOF), used in separation and concentration of silver ions.
  • Synthesis of N,N′-disubstituted dithiooxamides.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302

Hazard Classifications

Acute Tox. 4 Oral

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves

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Certificados de análisis (COA)

Lot/Batch Number
STBL3240
STBK7707
STBK7706
STBK0843
STBK0842

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Nickel (II) complexes with dithiooxamide, N, N'-di-methyl-and N, N'-di-hydroxyethyl-dithiooxamide.
Peyronel G, et al.
Inorgorganica Chimica Acta, 5, 627-633 (1971)
Preparation of Dithiooxamide Derivatives.
Hurd RN, et al.
The Journal of Organic Chemistry, 26(10), 3980-3987 (1961)
Xiang Zhu et al.
Chemical communications (Cambridge, England), 50(95), 15055-15058 (2014-10-21)
Thiazolothiazole-linked porous organic polymers have been synthesized from a facile catalyst-free condensation reaction between aldehydes and dithiooxamide under solvothermal conditions. The resultant porous frameworks exhibit a highly selective uptake of CO2 over N2 under ambient conditions.
Ayşen Demir Mülazımoğlu et al.
Sensors (Basel, Switzerland), 12(4), 3916-3928 (2012-06-06)
Electrochemical oxidation of quercetin, as an important biological molecule, has been studied in non-aqueous media using cyclic voltammetry, electrochemical impedance spectroscopy and scanning electron microscopy. To investigate the electrochemical properties of quercetin, an important flavonoid derivative, on a different surface
S Goto et al.
The Japanese journal of surgery, 14(2), 135-138 (1984-03-01)
An improved staining technique for acetylcholinesterase (AChE) activity using rubeanic acid was used to make a clinical diagnosis in 54 children with constipation. Nineteen were thus confirmed to have Hirschsprung's disease. False positive or negative reactions were nil. The sites
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