298441

Chloroborane methyl sulfide complex

• Sinónimos: Boron monochloride methyl sulfide complex, Chloro(dimethyl sulfide)dihydroboron, Monochloroborane-dimethyl sulfide, monoChloroborane methyl sulfide complex
• Fórmula lineal: (CH₃)₂S·BH₂Cl
• Número de CAS: 63348-81-2
• Peso molecular: 110.41
• MDL number: MFCD00013210
• UNSPSC Code: 12352101
• PubChem Substance ID: 24857987
• NACRES: NA.22

Propiedades

• Quality Level: 200
• reaction suitability: reagent type: reductant
• density: 1.059 g/mL at 25 °C (lit.)
• functional group: thioether
• SMILES string: C[S+](C)[BH2-]Cl
• InChI: 1S/C2H8BClS/c1-5(2)3-4/h3H2,1-2H3
• InChI key: CUKLQTNDSCOWTI-UHFFFAOYSA-N

Descripción

Application

Reactant for:

• Substitution reactions
• Boronation reactions
• Preparation of diborylamines
• Preparation of unsymmetrical borafluorenes via low-temperature carbon-hydrogen activation reactions
• Asymmetrical aldol reactions with a-chiral aldehydes
• Addition reaction with α-pinene

Reagent for hydroboration and synthesis of chlorodialkylboranes.

Información de seguridad

• pictograms: GHS02,GHS05
• signalword: Danger
• hcodes: H226,H314
• pcodes: P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Flam. Liq. 3 - Skin Corr. 1B
• supp_hazards: EUH014
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 3
• flash_point_f: 75.2 °F - closed cup
• flash_point_c: 24 °C - closed cup
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter