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278505

Sigma-Aldrich

Sulfuryl chloride solution

1.0 M in methylene chloride

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About This Item

Fórmula lineal:
SO2Cl2
Número de CAS:
7791-25-5
Peso molecular:
134.97
MDL number:
MFCD00011451
UNSPSC Code:
12352300
PubChem Substance ID:
24856819
NACRES:
NA.23

form

liquid

Quality Level

200

concentration

1.0 M in methylene chloride

density

1.352 g/mL at 25 °C

SMILES string

ClS(Cl)(=O)=O

InChI

1S/Cl2O2S/c1-5(2,3)4

InChI key

YBBRCQOCSYXUOC-UHFFFAOYSA-N

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Categorías relacionadas

Application


  • Palladium-Catalyzed Synthesis of Ammonium Sulfinates from Aryl Halides and a Sulfur Dioxide Surrogate: A Gas-and Reductant-Free Process: This study elaborates on using sulfuryl chloride for oxidative chlorination leading to sulfonyl chloride formation, which is important for synthetic organic chemistry (Emmett et al., 2014).

  • Combining Organometallic Reagents, the Sulfur Dioxide Surrogate DABSO, and Amines: A One‐Pot Preparation of Sulfonamides, Amenable to Array Synthesis: This research discusses an innovative one-pot method for preparing sulfonamides using sulfuryl chloride, highlighting its utility in streamlining complex syntheses (Deeming et al., 2015).

  • Interfacial polymerization: from chemistry to functional materials: The article illustrates the use of sulfuryl chloride in interfacial polymerization, a key technique for developing advanced materials with tailored properties (Zhang et al., 2020).

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1C - STOT SE 3

target_organs

Central nervous system

supp_hazards

EUH014

Storage Class

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
MKCV6148
MKCS3187
SHBP3369
MKCN9987
SHBN0676

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Sigma-Aldrich

320536

Thionyl chloride

Bicarbonato de sodio ACS reagent, ≥99.7%

Sigma-Aldrich

S6014

Bicarbonato de sodio

Azobisisobutyronitrile 12 wt. % in acetone

Sigma-Aldrich

768375

Azobisisobutyronitrile

Dietiléter contains 1 ppm BHT as inhibitor, anhydrous, ≥99.7%

Sigma-Aldrich

296082

Dietiléter

Qian Wu et al.
Chemical communications (Cambridge, England), 47(32), 9188-9190 (2011-07-14)
A new, efficient protocol for the synthesis of di(hetero)aryl sulfides is described. Cheap and easily available arylsulfonyl chlorides as a sulfur source reductively couple with electron-rich (hetero)arenes (e.g., indolizines, indoles, electron-rich benzenes, etc.) in the presence of triphenylphosphine to afford
Philippe Hermange et al.
Organic letters, 11(18), 4044-4047 (2009-08-15)
Reaction of an isoquinoline, a silyloxyfuran, and an acyl or sulfonyl chloride provides easy access to a wide variety of isoquinolinobutyrolactones with excellent yields and diastereoselectivites (R*,R* isomer), even in the case of formation of quaternary centers (i.e., R(3) or
Manli Zhang et al.
Chemical communications (Cambridge, England), 47(41), 11522-11524 (2011-09-29)
A palladium-catalyzed direct desulfitative C-arylation of a benzo[d]oxazole C-H bond with arene sulfonyl chlorides is described. The procedure tolerates halo, cyano, nitro, trifluoromethyl, acetyl and acetylamino groups on the phenyl ring of sulfonyl chlorides, providing the arylation products in moderate
Christopher Blackburn
ACS combinatorial science, 14(3), 150-154 (2012-02-11)
Reductive aminations and further transformations of an azo dye and fluorous tagged aldehyde are described. The intensely colored 2,4-dialkoxybenzyl protected amines undergo Fmoc-based peptide coupling, Suzuki reactions, and sulfonamide formation with product isolation facilitated by visual monitoring of fluorous solid
Polystyrene sulfonyl chloride: a highly orthogonal linker resin for the synthesis of nitrogen-containing heterocycles.
Matthias Mentel et al.
Angewandte Chemie (International ed. in English), 48(32), 5841-5844 (2009-07-08)
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