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399388

Sigma-Aldrich

Formic acid

greener alternative

ACS reagent, ≥88%

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About This Item

Linear Formula:
HCOOH
CAS Number:
Molecular Weight:
46.03
Beilstein:
1209246
EC Number:
MDL number:
UNSPSC Code:
12352106
PubChem Substance ID:
NACRES:
NA.21

grade

ACS reagent

Quality Level

vapor density

1.6 (vs air)

vapor pressure

44.8 mmHg ( 20 °C)

description

dilution test passes test

Assay

≥88%

form

liquid

autoignition temp.

1004 °F

expl. lim.

57 %

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

impurities

≤0.4% Acetic acid

evapn. residue

≤0.002%

color

APHA: ≤15

refractive index

n20/D 1.370 (lit.)

pH

2.2 (20 °C, 2.2 g/L)

bp

100-101 °C (lit.)

mp

8.2-8.4 °C (lit.)

solubility

water: miscible

density

1.22 g/mL at 25 °C (lit.)

anion traces

chloride (Cl-): ≤0.001%
sulfate (SO42-): ≤0.002%
sulfite (SO32-): passes test

cation traces

Fe: ≤5 ppm
NH4+: ≤0.005%
heavy metals: ≤5 ppm (by ICP)

greener alternative category

storage temp.

room temp

SMILES string

OC=O

InChI

1S/CH2O2/c2-1-3/h1H,(H,2,3)

InChI key

BDAGIHXWWSANSR-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Click here for more information.

Application

Reductant used in iron-catalyzed, greener reduction of aldehydes to alcohols .

Fast and selective iron-catalyzed transfer hydrogenations of aldehydes

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Supplementary Hazards

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

118.4 °F

Flash Point(C)

48 °C


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Palladium-Catalyzed Hydrocarboxylation of Alkynes with Formic Acid.
Hou J, et al.
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 127(21), 6400-6403 (2015)
Modification of Pd for formic acid decomposition by support grafted functional groups.
Jones S, et al.
Catalysis, Structure & Reactivity, 1(1), 19-24 (2015)
Raman spectral study of 'neat' formic acid and aqueous and organic solutions of formic acid.
Bartholomew RJ and Irish DE.
Journal of Raman Spectroscopy, 30(4), 325-334 (1999)
Direct formic acid fuel cells on Pd catalysts supported on hybrid TiO2-C materials.
Matos J, et al.
Applied Catalysis. B, Environmental, 163, 167-178 (2015)
Pd-Cu/C electrocatalysts synthesized by one-pot polyol reduction toward formic acid oxidation: Structural characterization and electrocatalytic performance.
Wang L, et al.
International Journal of Hydrogen Energy, 40(4), 1726-1734 (2015)

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