715301

Manganese bis(trifluoromethanesulfonate)

• Synonym(s): Manganese triflate, Manganese trifluoromethanesulfonate
• Empirical Formula (Hill Notation): C₂F₆MnO₆S₂
• CAS Number: 55120-76-8
• Molecular Weight: 353.08
• MDL number: MFCD17015267
• UNSPSC Code: 12161600
• PubChem Substance ID: 329762961
• NACRES: NA.22

Properties

• form: solid
• Quality Level: 100
• reaction suitability: core: manganese; reagent type: catalyst
• impurities: 5% metallic Mn
• mp: >400 °C
• SMILES string: FC(F)(F)S(=O)(=O)O[Mn]OS(=O)(=O)C(F)(F)F
• InChI: 1S/2CHF3O3S.Mn/c2*2-1(3,4)8(5,6)7;/h2*(H,5,6,7);/q;;+2/p-2
• InChI key: HEYNLDRKZOOEDN-UHFFFAOYSA-L

Description

General description

Manganese bis(trifluoromethanesulfonate) is also known as manganese triflate. It is used as a catalyst in organic synthesis for the oxidation of various hydrocarbons, epoxidation, and C-H oxidation reactions.

Application

Catalyst for:

• Biginelli reactions
• Methanolysis

Safety Information

• Pictograms: GHS05,GHS07
• Signal Word: Danger
• Hazard Statements: H302,H314
• Precautionary Statements: P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Skin Corr. 1B
• Storage Class Code: 8A - Combustible corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable