If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
240877
p-Toluenesulfonyl chloride
≥99%, solid, ReagentPlus®
Synonym(s):
TsCl, Tosyl chloride
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About This Item
Product Name
p-Toluenesulfonyl chloride, ReagentPlus®, ≥99%
vapor pressure
1 mmHg ( 88 °C)
Quality Segment
product line
ReagentPlus®
assay
≥99%
form
solid
bp
134 °C/10 mmHg (lit.)
mp
65-69 °C (lit.)
solubility
benzene: freely soluble(lit.), chloroform: freely soluble(lit.), ethanol: freely soluble(lit.), water: insoluble(lit.)
SMILES string
Cc1ccc(cc1)S(Cl)(=O)=O
InChI
1S/C7H7ClO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3
InChI key
YYROPELSRYBVMQ-UHFFFAOYSA-N
General description
Application
- In combination with N-methylimidazole for the esterification or thioesterification of carboxylic acids and alcohols or thiols.
- As an additive to enhance the yield of symmetrical biaryls via palladium chloride catalyzed homo-coupling of arylboronic acids in the absence of ligands.
- As a positive chlorine source for the ?-chlorination of ketones.
- Solvent-free tosylation of alcohols and phenols in the presence of heterodoxy acids.
- As an activator for reaction between 2-alkynylbenzaldoxime and phenols to form 1-aroxyisoquinolines in the presence of silver triflate.
- As a catalyst for the solvent-free preparation of symmetrical bis(benzhydryl)ethers from benzhydrols.
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| assay ≥99% | assay ≥98% | assay 97% | assay ≥98.0% (GC) |
| solubility benzene: freely soluble(lit.), ethanol: freely soluble(lit.), chloroform: freely soluble(lit.), water: insoluble(lit.) | solubility - | solubility - | solubility - |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
| form solid | form - | form - | form solid |
| mp 65-69 °C (lit.) | mp 65-69 °C (lit.) | mp - | mp 67 °C |
| bp 134 °C/10 mmHg (lit.) | bp 134 °C/10 mmHg (lit.) | bp 252-253 °C (lit.) | bp - |
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signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1
flash_point_f
262.4 °F - closed cup
flash_point_c
128 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Storage Class
11 - Combustible Solids
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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