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203025

Sigma-Aldrich

Cesium chloride

≥99.999% trace metals basis

Synonym(s):

Caesium chloride, Cesium monochloride

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About This Item

Linear Formula:
CsCl
CAS Number:
Molecular Weight:
168.36
EC Number:
MDL number:
UNSPSC Code:
12352302
eCl@ss:
38050206
PubChem Substance ID:
NACRES:
NA.23
grade:
for analytical purposes
form:
crystalline
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grade

for analytical purposes

Assay

≥99.999% trace metals basis

form

crystalline

impurities

≤10.0 ppm Trace Metal Analysis

mp

645 °C (lit.)

SMILES string

[Cl-].[Cs+]

InChI

1S/ClH.Cs/h1H;/q;+1/p-1

InChI key

AIYUHDOJVYHVIT-UHFFFAOYSA-M

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General description

Cesium chloride is a highly water soluble crystalline solid withhigh refractive index and dielectric properties. It is widely used in the fieldof solid oxide fuel cells and lighting devices. [1] [2]

Application

Cesium chloride can be used:
  • As crystal seeds to enhance the coverage of the CH3NH3PbI3−xClx absorber layer in perovskite solar cells. It helps to boost the power conversion efficiency of solar cells.[1]
  • As a medium to synthesize N and P-codoped carbon nanospheres for application in fuel cells and zinc-air batteries.[3]
  • To fabricate silicon nanopillars for solar cells, batteries, light-emitting diodes, etc.[4]
  • To enhance the thermal stability of polyoxometalates(used as electrode materials for lithium-ion batteries).[2]
  • To synthesize the lead-free halide double perovskite Cs2AgInCl6 with excellent moisture, light, and heat resistance. This material shows great potential for various optoelectronic applications, including photovoltaics.[5]

Pictograms

Health hazard

Signal Word

Warning

Hazard Statements

Hazard Classifications

Repr. 2

Storage Class Code

13 - Non Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

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Effect of cesium chloride modification on the film morphology and UV-induced stability of planar perovskite solar cells
Wenzhe Li, et al.
Journal of Materials Chemistry, 4, 11688-11695 (2016)
Fabrication and reflection properties of silicon nanopillars by cesium chloride self-assembly and dry etching
Jing Liu, et al
Applied Surface Science, 258, 8825-8830 (2012)
Composition design, optical gap and stability investigations of lead-free halide double perovskite Cs2AgInCl 6
Jun Zhou, et al.
Journal of Materials Chemistry, 5, 15031-15037 (2017)
Study of Polyoxometalates as Electrode Materials for Lithium-Ion Batteries: Thermal Stability Paves the Way to Improved Cycle Stability}
Georg-Maximilian Bosch, et al.
ChemElectroChem, 8, 656-664 (2021)
A Metal-Free N and P-Codoped Carbon Nanosphere as Bifunctional Electrocatalyst for Rechargeable Zinc-Air Batteries
Ping Li, et al.
ChemElectroChem, 6, 393-397 (2019)

Articles

Colloidal quantum dots (CQDs) are semiconducting crystals of only a few nanometers (ca. 2–12 nm) coated with ligand/surfactant molecules to help prevent agglomeration.

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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