72568
Nitrilotri(methylphosphonic acid)
≥95% (T)
Synonym(s):
ATMP, Aminotris(methylenephosphonic acid), [Bis(phosphonomethyl)amino]methylphosphonic acid
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About This Item
Linear Formula:
N[CH2PO(OH)2]3
CAS Number:
Molecular Weight:
299.05
Beilstein:
1715724
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥95% (T)
form
crystals
mp
~215 °C (dec.)
functional group
amine
SMILES string
OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O
InChI
1S/C3H12NO9P3/c5-14(6,7)1-4(2-15(8,9)10)3-16(11,12)13/h1-3H2,(H2,5,6,7)(H2,8,9,10)(H2,11,12,13)
InChI key
YDONNITUKPKTIG-UHFFFAOYSA-N
Application
Nitrilotri(methylphosphonic acid) is a common chelating agent used in synthetic chemistry. Some of the other applications include:
- Preparation of hexagonal porous three-dimensional structures encapsulating a template, layered structures with intercalated templates or linear polymers.
- Synthesis of metal-organic frameworks in combination with uranyl nitrate.
- Preparation of ingredient of anticorrosive protective coatings on the steel surface.
- ATMP can also be employed as a scale inhibitor during squeeze treatments in oilfield operations.
Other Notes
Powerful complexing agent
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Met. Corr. 1
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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[Hygienic establishment of maximum permissible concentrations of nitrilotrimethylphosphonic acid and a copper-containing complex in reservoir water].
R A Suleĭmanov et al.
Gigiena i sanitariia, (2)(2), 67-68 (1984-02-01)
Synthesis, structure, and properties of nitrilo-tris (methylenephosphonato)-triaquairon (II){Fe [μ-NH (CH 2 PO 3 H) 3](H 2 O) 3}, as an ingredient of anticorrosive protective coatings on the steel surface.
Somov N V, et al.
Crystallography Reports, 60(6), 853-859 (2015)
Nitrilotris (methylenephosphonato) potassium K [μ6-NH (CH2PO3) 3H4]: Synthesis, structure, and the nature of the K?O chemical bond.
Somov N V, et al.
Crystallography Reports, 61(4), 606-610 (2016)
P K Bali et al.
Archives of biochemistry and biophysics, 281(2), 251-256 (1990-09-01)
The kinetics of iron removal from human serum diferric transferrin by nitrilotris(methylenephosphonic acid) (NTP) and pyrophosphate (PPi) have been studied in 0.1 M, pH 7.4, N-(2-hydroxyethyl)piperazine-N'-2-ethanesulfonate buffer at 25 degrees C using urea/polyacrylamide gel electrophoresis. The four microscopic rate constants
Yuta Suzuki et al.
Nucleic acids symposium series (2004), (52)(52), 379-380 (2008-09-09)
Only one phosphodiester linkage in long DNA was hydrolyzed simply by using two components: oligonucleotide-multiphosphonate conjugates ("gapmers") and Ce(IV)/EDTA (Fig. 1).
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