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P3754

Sigma-Aldrich

1,4-Bis(5-phenyl-2-oxazolyl)benzene

BioReagent, suitable for scintillation

Synonym(s):

1,4-Bis(5-phenyl-2-oxazolyl)benzene, 2,2′-p-Phenylene-bis(5-phenyloxazole), Di(phenyl-5-oxazolyl-2)-1,4-benzene, POPOP

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About This Item

Empirical Formula (Hill Notation):
C24H16N2O2
CAS Number:
1806-34-4
Molecular Weight:
364.40
Beilstein:
325741
EC Number:
217-304-6
MDL number:
MFCD00005309
UNSPSC Code:
41116105
PubChem Substance ID:
24898445
NACRES:
NA.32

product line

BioReagent

form

powder

mp

242-246 °C (lit.)

suitability

suitable for scintillation

SMILES string

c1ccc(cc1)-c2cnc(o2)-c3ccc(cc3)-c4ncc(o4)-c5ccccc5

InChI

1S/C24H16N2O2/c1-3-7-17(8-4-1)21-15-25-23(27-21)19-11-13-20(14-12-19)24-26-16-22(28-24)18-9-5-2-6-10-18/h1-16H

InChI key

MASVCBBIUQRUKL-UHFFFAOYSA-N

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General description

1,4-Bis(5-phenyl-2-oxazolyl) benzene, also known as POPOP, is a well-known scintillation luminophore. It is an efficient fluorescent organic compound with high stokes shift. The POPOP dye is photostable in polar protic and polar aprotic solvents. The resulting photochemical quantum yield and the photodecomposition rate depend on the solvent′s electron affinity.

Application

1,4-Bis(5-phenyl-2-oxazolyl) benzene or POPOP is widely used to detect radioactivity by scintillation counting.

Features and Benefits

1,4-Bis(5-phenyl-2-oxazolyl) benzene or POPOP has the following advantages:

  • High fluorescence quantum yield.
  • High molar absorptivity.
  • Large Stokes Shift.
  • High Photostability in most organic solvents.

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Description
Pricing

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H302,H319

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Juliana Oliveira et al.
ACS applied materials & interfaces, 10(15), 12904-12912 (2018-03-28)
Organic photodetectors (PDs) based on printing technologies will allow to expand the current field of PD applications toward large-area and flexible applications in areas such as medical imaging, security, and quality control, among others. Inkjet printing is a powerful digital
N S Kudryasheva et al.
Luminescence : the journal of biological and chemical luminescence, 16(3), 243-246 (2001-06-16)
The involvement of upper electron-excited states in bacterial bioluminescence process was studied with excitation energy-accepting molecules. The fluorescent aromatic compounds, anthracene and 1.4-bis(5-phenyloxazol-2-yl)benzene, were chosen. Energies of their lowest excited singlet states are higher than the energy of the analogous
Xiaohui Hou et al.
Analytical biochemistry, 368(1), 100-110 (2007-06-15)
In this study, micron-sized poly(styrene-co-glycidyl methacrylate) (PSt-GMA) fluorescent microspheres of 5.1microm in diameter were synthesized via dispersion polymerization of styrene and glycidyl methacrylate in the presence of 1,4-bis(5-phenyloxazol-2-yl) benzene (POPOP), which provided surface functional groups for covalent immobilization of enzymes.
Kadir Aslan et al.
Analytical chemistry, 80(19), 7304-7312 (2008-09-04)
The use of zinc thin films deposited onto glass supports for surface plasmon coupled fluorescence (SPCF) over a broad 200 nm wavelength range is demonstrated. Fresnel calculations performed in the ultraviolet and visible spectral range are predicted to generate surface
J C Stockert et al.
Acta histochemica, 99(2), 195-205 (1997-06-01)
N-quaternary derivatives of the diaryloxazole scintillators POPOP and dimethyl-POPOP (dmPOPOP) in chloroform solution were obtained by methylation with dimethylsulfate. After drying, aqueous solutions of the corresponding oxazolium compounds (Q-POPOP and Q-dmPOPOP) revealed strong fluorescence (peaks at 485 and 493 nm
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