90161
(2,2′)-Furildioxime
for spectrophotometric det. of Au(II), Co(II), Cu(II), Ni(II), Pd(II), Re(VII), U(VI), ≥97.0% (sum of isomers, HPLC)
Synonym(s):
Bis(2-furyl)glyoxime
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About This Item
Empirical Formula (Hill Notation):
C10H8N2O4
CAS Number:
Molecular Weight:
220.18
EC Number:
MDL number:
UNSPSC Code:
12000000
PubChem Substance ID:
NACRES:
NA.21
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description
mixture of isomers
Assay
≥97.0% (sum of isomers, HPLC)
form
crystals
technique(s)
UV/Vis spectroscopy: suitable
SMILES string
O\N=C(c1ccco1)\C(=N\O)c2ccco2
InChI
1S/C10H8N2O4/c13-11-9(7-3-1-5-15-7)10(12-14)8-4-2-6-16-8/h1-6,13-14H/b11-9+,12-10+
InChI key
RBOZTFPIXJBLPK-WGDLNXRISA-N
General description
Oximes are selective reagents which react with limited number of metal ions. These form water-insoluble complexes extractable into organic solvents. Furildioxime, a gravimetric and colorimetric reagent for nickel, palladium, platinum and rhenium is prepared by the oximation of furil with hydroxyammonium chloride followed by aqueous recrystallisation using MacKair′s method.
Application
a-furildioxime [(2,2′)-Furildioxime] was used:
- as neutral carrier in Calcium(II)-selective potentiometric sensor, selective electrode used for titration.
- in the synthesis of ketenimines and bis(ketenimines).
- in determination of palladium in water samples by rapid spectrophotometric analysis.
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Rapid spectrophotometric determination of trace amounts of palladium in water samples after dispersive liquid-liquid microextraction.
Kozani, Reyhaneh Rahnama, Jamshid Mofid-Nakhaei, and Mohammad Reza Jamali.
Environmental Monitoring and Assessment, 185, 6531-6537 (2013)
D L Bissett et al.
Journal of the American Academy of Dermatology, 35(4), 546-549 (1996-10-01)
Iron is a factor in skin photodamage, apparently by way of its participation in oxygen radical production. Certain topical iron chelators are photoprotective. Our purpose was to determine the level of topical photoprotection provided by the iron chelator 2-furildioxime (FDO)
D L Bissett et al.
Journal of the American Academy of Dermatology, 31(4), 572-578 (1994-10-01)
In previous work we found that iron is a factor in skin photodamage, apparently by way of its participation in oxygen radical production. Here we report topical photoprotection with the iron chelator 2-furildioxime (FDO). Our purpose was to determine the
H Mitani et al.
European journal of pharmacology, 411(1-2), 169-174 (2001-01-04)
Kojic acid, a fungal metabolic product, has been used as a skin-depigmenting agent in skin care products marketed in Japan. Iron in the skin is known to be involved in wrinkling as a result of chronic photodamage. Kojic acid was
Najma Memon et al.
TheScientificWorldJournal, 2012, 418047-418047 (2012-06-02)
A very simple, selective, and fast flow injection spectrophotometeric method is developed for determination of nickel using furildioxime as complexing agent. Micellar solution of brij-35 is employed to solubilize the sparingly soluble complex of Ni-furildioxime in buffered aqueous system (pH-9.00).
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