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D176605

Sigma-Aldrich

4,5-Dimethyl-1,2-phenylenediamine

98%

Synonym(s):

4,5-Diamino-o-xylene

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About This Item

Linear Formula:
(CH3)2C6H2(NH2)2
CAS Number:
Molecular Weight:
136.19
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

Assay

98%

form

powder

mp

127-129 °C (lit.)

storage temp.

2-8°C

SMILES string

Cc1cc(N)c(N)cc1C

InChI

1S/C8H12N2/c1-5-3-7(9)8(10)4-6(5)2/h3-4H,9-10H2,1-2H3

InChI key

XSZYBMMYQCYIPC-UHFFFAOYSA-N

Application

Employed in the preparation of transition metal complexes and quinoxalinones.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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K Mori et al.
Chemical & pharmaceutical bulletin, 46(9), 1474-1476 (1998-10-17)
A simple and accurate method for determination of vitamin C (ascorbic acid (AsA) and dehydroascorbic acid (DHA)) using 4,5-dimethyl-o-phenylenediamine (DMPD) was investigated. It was found that DMPD is a useful fluorescent reagent. The reaction product of DMPD with DHA showed
E Mikiciuk-Olasik et al.
Acta poloniae pharmaceutica, 51(3), 231-233 (1994-01-01)
Some of new derivatives of 4-acylquinoxalin-2-one obtained in the reaction of N,N'-bis(chloroacetyl)-4,5-dimethyl-o-phenylenediamine with primary amines are described. Compounds were tested for their anti-HIV activity and as ligands for 99mTc.
Tijana Bugarcic et al.
Inorganic chemistry, 48(19), 9444-9453 (2009-09-29)
The synthesis and characterization of ruthenium(II) arene complexes of the general formula [(eta(6)-arene)Ru(XY)Z](+), where arene = p-cymene (p-cym), hexamethylbenzene (hmb), or biphenyl (bip), XY = o-phenylenediamine (o-pda), o-benzoquinonediimine (o-bqdi), or 4,5-dimethyl-o-phenylenediamine (dmpda), and Z = Cl, Br, or I, are
M L Karnovsky et al.
Environmental health perspectives, 102 Suppl 10, 43-44 (1994-12-01)
Although great progress has been made in understanding the respiratory burst of leukocytes that produce superoxide (O2-), it is possible that a component or components, might have been overlooked. Furthermore, O2- production and its sequels, though cardinal in bactericidal action
M G Gioia et al.
Journal of pharmaceutical and biomedical analysis, 48(2), 331-339 (2008-02-26)
A reversed-phase ion pair liquid chromatographic method (RP-LC) for the determination of dehydroascorbic acid (DHA) and ascorbic acid (AA) and also acetaminophen, which is combined in pharmaceuticals, is proposed and validated. AA and acetaminophen were analyzed directly, while DHA was

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