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524670

Sigma-Aldrich

Luperox® DHD-9, 2-Butanone peroxide solution

~32 wt. % in phthalate-free plasticizer mixture

Synonym(s):

2-Butanone peroxide solution, Methyl ethyl ketone peroxide solution

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About This Item

Linear Formula:
C2H5C(OOH)(CH3)OOC(OOH)(CH3)C2H5
CAS Number:
1338-23-4
Molecular Weight:
210.22
Beilstein:
1759757
MDL number:
MFCD00042641
UNSPSC Code:
12162002
PubChem Substance ID:
24874434
NACRES:
NA.23

Quality Level

100

reaction suitability

reagent type: oxidant

concentration

~32 wt. % in phthalate-free plasticizer mixture

refractive index

n20/D 1.437

density

0.99 g/mL at 25 °C

storage temp.

2-8°C

SMILES string

CCC(C)(OO)OOC(C)(CC)OO

InChI

1S/C8H18O6/c1-5-7(3,11-9)13-14-8(4,6-2)12-10/h9-10H,5-6H2,1-4H3

InChI key

WFUGQJXVXHBTEM-UHFFFAOYSA-N

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Related Categories

Application

Polymerization initiator

Legal Information

Product of Arkema Inc.
Luperox is a registered trademark of Arkema Inc.

Signal Word

Danger

Hazard Statements

H242,H314,H361d,H412

Hazard Classifications

Aquatic Chronic 3 - Eye Dam. 1 - Org. Perox. D - Repr. 2 - Skin Corr. 1B

Storage Class Code

5.2 - Organic peroxides and self-reacting hazardous materials

WGK

WGK 1

Flash Point(F)

165.2 °F - closed cup

Flash Point(C)

74 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
MKCV6835
MKCW1945
MKCW9542
MKCV3733
MKCT0678

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M N Bozdemir et al.
Human & experimental toxicology, 30(12), 2002-2006 (2011-04-22)
Although ingestion of methyl ethyl ketone peroxide (MEKP) is rare, it carries a high risk of morbidity and mortality. This paper reports the first such case from Turkey in which a 70-year-old man unintentionally ingested MEKP in his kitchen. The
[An organic peroxide, methyl ethyl ketone peroxide, damage to cytochrome P-450 peroxidase and microsomal enzymes activity].
M Ando
Nihon eiseigaku zasshi. Japanese journal of hygiene, 41(2), 587-592 (1986-06-01)
Jing Zhang et al.
Journal of hazardous materials, 181(1-3), 1024-1030 (2010-06-18)
Methyl ethyl ketone peroxide (MEKPO) is widely used in polymer industry. It is highly sensitive to heat, friction, shock, flame or other sources of ignition, causing risks in production, storage and transportation. In this article, MEKPO is synthesized at a
P J Karhunen et al.
Human & experimental toxicology, 9(3), 197-200 (1990-05-01)
Fatal massive peripheral zonal hepatic necrosis developed in a 47-year-old man who accidentally ingested a solution of methyl ethyl ketone peroxide (MEKP) in dimethyl phthalate. Such solutions contain about 10% active oxygen. The clinical course was characterized by temporary cardiac
M Ando et al.
Toxicology and applied pharmacology, 81(3 Pt 1), 517-524 (1985-12-01)
Some new aspects of damage to cytochrome P-450 peroxidase activities by a toxic peroxide were investigated. Methyl ethyl ketone peroxide (MEKP) damage to cytochrome P-450 and inhibition of cytochrome P-450-mediated peroxidase activities were studied. In vivo, hepatic microsomal NADH- and
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