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Key Documents

522902

Sigma-Aldrich

(S)-(+)-2-Methylpiperidine

97%

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About This Item

Empirical Formula (Hill Notation):
C6H13N
CAS Number:
Molecular Weight:
99.17
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

97%

optical activity

[α]20/D +35°, c = 3.5 in hexane

refractive index

n20/D 1.446 (lit.)

bp

117-121 °C (lit.)

density

0.823 g/mL at 25 °C (lit.)

SMILES string

C[C@H]1CCCCN1

InChI

1S/C6H13N/c1-6-4-2-3-5-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1

InChI key

NNWUEBIEOFQMSS-LURJTMIESA-N

Application

(S)-(+)-2-Methylpiperidine has been used in the preparation of (S)-N-(3-(2-pipecolin-1-yl)propyl)phthalimide by reacting with N-(3-bromopropyl)phthalimide. It may also be used as a starting material in the multi-step synthesis of (2S,6S)-(+)-solenopsin A.

Pictograms

FlameExclamation mark

Signal Word

Danger

Hazard Statements

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

60.0 °F - closed cup

Flash Point(C)

15.56 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Anodic Cyanation of (-)-N-Phenyl-2-Methylpiperidine: A Short Synthesis of (+)-Solenopsin A and (+)-Isosolenopsin A.
Girard N, et al.
Synthetic Communications, 35(5), 711-723 (2005)
Noncyclam Tetraamines Inhibit CXC Chemokine Receptor Type 4 and Target Glioma-Initiating Cells.
Ros-Blanco L, et al.
Journal of Medicinal Chemistry, 55(17), 7560-7570 (2012)

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