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Key Documents

8.00590

Sigma-Aldrich

Methyl methacrylate

(stabilised) for synthesis

Synonym(s):

Methyl methacrylate, Methyl 2-methylpropenoate, Methacrylic acid methyl ester, MMA

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Estimated to ship onMarch 20, 2025


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100 ML
$44.40
1 L
$75.40
2.5 L
$164.00

About This Item

Linear Formula:
CH2=C(CH3)COOCH3
CAS Number:
Molecular Weight:
100.12
MDL number:
UNSPSC Code:
12352108
EC Index Number:
201-297-1
NACRES:
NA.22

$44.40


Estimated to ship onMarch 20, 2025


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vapor pressure

53 hPa ( 20 °C)

Quality Level

assay

≥99.0% (GC)

form

liquid

autoignition temp.

430 °C

potency

7872 mg/kg LD50, oral (Rat)
>5000 mg/kg LD50, skin (Rabbit)

expl. lim.

2.1-12.5 % (v/v)

bp

101 °C/1013 hPa

mp

-48 °C

transition temp

flash point 10 °C

density

0.94 g/cm3 at 20 °C

storage temp.

2-30°C

SMILES string

O(C)C(=O)C(=C)C

InChI

1S/C5H8O2/c1-4(2)5(6)7-3/h1H2,2-3H3

InChI key

VVQNEPGJFQJSBK-UHFFFAOYSA-N

Application



  • Catalysis for the synthesis of methacrylic acid and methyl methacrylate: Explored esterification processes for producing methyl methacrylate, significant for industrial scale production (MJD Mahboub et al., 2018).




Analysis Note

Assay (GC, area%): ≥ 99.0 % (a/a)
Density (d 20 °C/ 4 °C): 0.942 - 0.944
Identity (IR): passes test
The material is stabilised with hydroquinone monomethyl ether.
At time of analytical testing a content of >10 ppm stabiliser was determined.

pictograms

FlameExclamation mark

signalword

Danger

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 1

flash_point_f

50.0 °F - closed cup

flash_point_c

10 °C - closed cup


Certificates of Analysis (COA)

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Questions

1–2 of 2 Questions  
  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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