41239
D-Apiose
≥99.0% (HPLC)
Sinónimos:
3-C-Hydroxymethyl-D-glycero-tetrose
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About This Item
Fórmula empírica (notación de Hill):
C5H10O5
Número de CAS:
Peso molecular:
150.13
MDL number:
UNSPSC Code:
12352201
PubChem Substance ID:
NACRES:
NA.25
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Quality Level
assay
≥99.0% (HPLC)
concentration
100-1000 mM in H2O
storage temp.
room temp
SMILES string
OC[C@@]1(O)COC(O)[C@@H]1O
InChI
1S/C5H10O5/c6-1-5(9)2-10-4(8)3(5)7/h3-4,6-9H,1-2H2/t3-,4?,5+/m0/s1
InChI key
ASNHGEVAWNWCRQ-LJJLCWGRSA-N
Application
D-Apiose, a plant-specific branched-chain monosaccharide found in rhamnogalacturonan II (RG-II), apiogalacturonan, and several apioglycosides, serves as a borate binding site for crosslinking of galacturonans within plant cell walls.
Packaging
Pack size based on mg solid
Storage Class
12 - Non Combustible Liquids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves
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Michael Mølhøj et al.
The Plant journal : for cell and molecular biology, 35(6), 693-703 (2003-09-13)
d-Apiose is a plant-specific branched-chain monosaccharide found in rhamnogalacturonan II (RG-II), apiogalacturonan, and several apioglycosides. Within RG-II, d-apiose serves as the binding site for borate, which leads to the formation of cross-links within the wall. Biochemical studies in duckweed and
Mayumi Kataoka et al.
Nucleic acids symposium series (2004), (52)(52), 281-282 (2008-09-09)
Here, we report the synthesis of 3'-deoxyapionucleoside 3''-triphosphates (apioNTPs) and the analysis of their property as substrate of enzymatic polymerization. We established the large scale synthetic route of 3-deoxy-D-apiose from D-galactose, and regio- and stereo-selective glycosylation procedures. Resulting 3'-deoxyapionucleosides were
Sergey A Nepogodiev et al.
Organic & biomolecular chemistry, 9(19), 6670-6684 (2011-08-19)
Fragments of pectic polysaccharides rhamnogalacturonan-II (RG-II) and apiogalacturonan were synthesised using p-tolylthio apiofuranoside derivatives as key building blocks. Apiofuranose thioglycosides can be conveniently prepared by cyclization of the corresponding dithioacetals possessing a 2,3-O-isopropylidene group, which is required for preservation of
E A Giunter et al.
Prikladnaia biokhimiia i mikrobiologiia, 44(1), 117-122 (2008-05-22)
Callus lines of common duckweed produced acid arabinogalactan and pectin in an amount varying from 1 to 3% of dry weight. The arabinogalactan specimens from the cell lines studied displayed a similar monosaccharide composition. The duckweed callus lines whose arabinogalactans
Chang Hyun Oh et al.
Nucleosides, nucleotides & nucleic acids, 25(8), 871-878 (2006-08-12)
Novel vinyl branched apiosyl nucleosides were synthesized in this study. Apiosyl sugar moiety was constructed by sequential ozonolysis and reductions. The bases (uracil and thymine) were efficiently coupled by glycosyl condensation procedure (persilyated base and TMSOTf). The antiviral activities of
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