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MilliporeSigma

73137

Supelco

2,2-Dimethoxypropane

analytical standard

Sinónimos:

Acetone dimethyl acetal

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About This Item

Fórmula lineal:
(CH3)2C(OCH3)2
Número de CAS:
Peso molecular:
104.15
Beilstein/REAXYS Number:
635678
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.02

grade

analytical standard

Quality Level

vapor density

3.59 (vs air)

vapor pressure

60 mmHg ( 15.8 °C)

assay

≥99.4% (GC)

shelf life

limited shelf life, expiry date on the label

expl. lim.

31 %, 58 °F
6 %, 27 °F

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

refractive index

n20/D 1.378 (lit.)
n20/D 1.378

bp

79-81 °C
83 °C (lit.)

density

0.847 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

SMILES string

COC(C)(C)OC

InChI

1S/C5H12O2/c1-5(2,6-3)7-4/h1-4H3

InChI key

HEWZVZIVELJPQZ-UHFFFAOYSA-N

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General description

2,2-Dimethoxypropane is an organic compound, which may be used as a protecting agent in the process of the synthesis of structurally related alkaloids like narciclasine and lycoricidine using phenylbromide as the starting material.

Application

2,2-Dimethoxypropane may be used as an analytical standard for the determination of the analyte in biological samples by headspace gas chromatography-mass spectrometry (HS-GC/MS) technique.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 2

supp_hazards

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

14.0 °F - closed cup

flash_point_c

-10 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Certificados de análisis (COA)

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Los clientes también vieron

Total Synthesis of Lycoricidine and Narciclasine by Chemical Dearomatization of Bromobenzene
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Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 129(47), 15245-15248 (2017)
Quantitative determination of n-propane, iso-butane, and n-butane by headspace GC-MS in intoxications by inhalation of lighter fluid
Bouche MPLA, et al.
Journal of Analytical Toxicology, 26(1), 35-42 (2002)
Determination of individual human faecal bile acids by gas-liquid chromatography after enzymatic deconjugation and simultaneous solvolysis and methylation using dimethoxypropane.
A van Faassen et al.
Clinica chimica acta; international journal of clinical chemistry, 152(1-2), 231-239 (1985-10-31)
Vladimir A Khripach et al.
Steroids, 75(1), 27-33 (2009-09-30)
Preparation of partially protected brassinosteroids is achieved through the reaction of the source material (24-epicastasterone and 24-epibrassinolide) with diol-specific reagents (2,2-dimethoxypropane and methylboronic acid). The obtained products were shown to be useful synthetic intermediates for further preparation of minor representatives
K Conway et al.
Biotechnic & histochemistry : official publication of the Biological Stain Commission, 74(1), 20-26 (1999-04-06)
Chemical dehydration can be accomplished using 2,2-dimethoxypropane (DMP). In the presence of an acid catalyst, this liquid reacts with water generating methanol and acetone as products. Although DMP is more expensive per milliliter than ethanol and other solvents used for

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