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MilliporeSigma

31659

Supelco

o-Tolidine

analytical standard

Sinónimos:

3,3′-Dimethylbenzidine, 4,4′-Bianisidine

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About This Item

Fórmula lineal:
[-C6H3(CH3)-4-NH2]2
Número de CAS:
Peso molecular:
212.29
Beilstein/REAXYS Number:
2210640
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:
NACRES:
NA.24

grade

analytical standard

Quality Level

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

128-131 °C (lit.)

application(s)

cleaning products
cosmetics
food and beverages
personal care

format

neat

SMILES string

Cc1cc(ccc1N)-c2ccc(N)c(C)c2

InChI

1S/C14H16N2/c1-9-7-11(3-5-13(9)15)12-4-6-14(16)10(2)8-12/h3-8H,15-16H2,1-2H3

InChI key

NUIURNJTPRWVAP-UHFFFAOYSA-N

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General description

o-Tolidine is widely used in the aniline dye industry for the synthesis of different azo dyes.

Application

o-Tolidine (3,3′-dimethylbenzidine) may be used as an analytical reference standard for the determination of the analyte formed from azo colorants in toy products by high-performance liquid chromatography with UV detection.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Reactivo colorimétrico sensible para oro y cloro libre en agua.

Warning

Puede ser cancerígeno.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

212.0 °F - closed cup

flash_point_c

100 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges


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Certificados de análisis (COA)

Lot/Batch Number

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1 of 2

Carcinogenic properties of orthotolidine (3, 3?-dimethylbenzidine).
Pliss GB and Zabezhinsky MA
Journal of the National Cancer Institute, 45(2), 283- 295 (1970)
Determination of aromatic amines formed from azo colorants in toy products.
Garrigos MC
Journal of Chromatography A, 976(1-2), 309-317 (2002)
Dyes metabolized to 3,3'-dimethylbenzidine (3,3'-dimethylbenzidine dye class.
Report on carcinogens : carcinogen profiles, 10, 105-106 (2004-08-25)
Zhijun Cao et al.
Biosensors & bioelectronics, 23(3), 348-354 (2007-06-06)
The electrooxidation of o-tolidine (oTD) was investigated via the electrochemical quartz crystal microbalance (EQCM) technique. The formation and breakage of the poorly soluble charge-transfer complex (CTC) occurred during the redox switching of oTD, and the CTC precipitation on and its
A K Cook et al.
American journal of veterinary research, 53(10), 1749-1751 (1992-10-01)
To evaluate the effect of diet on results obtained by use of 2 commercial test kits for detection of occult blood in feces, 5 dogs were fed 7 diets in randomized sequence. Dry and canned diets with various principal ingredients

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