21287

(−)-Camphanic acid chloride

for chiral derivatization, LiChropur^™, ≥98.0%

• Sinónimos: (−)-Camphanoyl chloride, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride
• Fórmula lineal: C₁₀H₁₃O₃Cl
• Número de CAS: 39637-74-6
• Peso molecular: 216.66
• Beilstein/REAXYS Number: 3590860
• EC Number: 254-552-4
• MDL number: MFCD00135626
• UNSPSC Code: 23151817
• PubChem Substance ID: 329752132
• NACRES: NA.22

Propiedades

• grade: for chiral derivatization
• Quality Level: 100
• product line: ChiraSelect^™
• assay: ≥98.0% (AT); ≥98.0%
• form: solid
• optical activity: [α]20/D −18±1°, c = 2% in carbon tetrachloride
• optical purity: enantiomeric ratio: ≥99.5:0.5 (GC)
• quality: LiChropur^™
• technique(s): HPLC: suitable
• mp: 67-70 °C; 71-73 °C (lit.)
• storage temp.: −20°C
• SMILES string: CC1(C)[C@@]2(C)CC[C@@]1(OC2=O)C(Cl)=O
• InChI: 1S/C10H13ClO3/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3/t9-,10+/m0/s1
• InChI key: PAXWODJTHKJQDZ-VHSXEESVSA-N

Descripción

General description

(1S)-(-)-Camphanic chloride is a derivatizing agent.

Application

(1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.

Other Notes

Reactivo derivatizante quiral para la determinación de pureza enantiomérica de alcoholes y aminas por HPLC

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Legal Information

ChiraSelect is a trademark of Sigma-Aldrich Co. LLC

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Información de seguridad

• pictograms: GHS05
• signalword: Danger
• hcodes: H314
• pcodes: P260 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P363
• Hazard Classifications: Skin Corr. 1B
• Storage Class: 8A - Combustible corrosive hazardous materials
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges