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03-4991

tert-Butyl hydroperoxide solution

Name: <I>tert</I>-Butyl hydroperoxide solution
Brand: SAJ

CP

Sinónimos:

1,1-Dimethylethyl hydroperoxide, 2-Hydroperoxy-2-methylpropane, TBHP

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Acerca de este artículo

Fórmula lineal:

(CH₃)₃COOH

Número CAS:

75-91-2

Peso molecular:

90.12

EC Number:

200-915-7

UNSPSC Code:

12352120

PubChem Substance ID:

329747725

Beilstein/REAXYS Number:

1098280

MDL number:

MFCD00002130

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Propiedades

grade

form

liquid

availability

available only in Japan

concentration

69 wt. % in H₂O

pH

4.3

SMILES string

CC(C)(C)OO

InChI

1S/C4H10O2/c1-4(2,3)6-5/h5H,1-3H3

InChI key

CIHOLLKRGTVIJN-UHFFFAOYSA-N

Descripción

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Este artículo	416665	8.14006	418064
Sigma-Aldrich 03-4991 tert-Butyl hydroperoxide solution	Sigma-Aldrich 416665 tert-Butyl hydroperoxide solution	Sigma-Aldrich 8.14006 tert-Butyl hydroperoxide	Sigma-Aldrich 418064 tert-Butyl hydroperoxide solution
concentration 69 wt. % in H₂O	concentration 5.0-6.0 M in decane, 55.4-65.1% (Thiosulphate, titration)	concentration 67.0-73.0% (iodometric)	concentration 5.0-6.0 M in nonane
pH 4.3	pH -	pH -	pH -
grade CP	grade -	grade synthesis grade	grade -
form liquid	form liquid	form liquid	form liquid
availability available only in Japan	availability -	availability -	availability -

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pictograms

GHS02,GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H226,H242,H302,H311,H314,H317,H330,H335,H341,H411

pcodes

P210 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338 - P370 + P378

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Eye Dam. 1 - Flam. Liq. 3 - Muta. 2 - Org. Perox. F - Skin Corr. 1C - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Clase de almacenamiento

5.2 - Organic peroxides and self-reacting hazardous materials

wgk

WGK 3

flash_point_f

107.6 °F - closed cup

flash_point_c

42 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number

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Metal-free, highly efficient organocatalytic amination of benzylic C-H bonds.

Qicai Xue et al.

Chemical communications (Cambridge, England), 49(35), 3700-3702 (2013-03-29)

A new synthetic approach toward direct C-N bond formation through sp(3) C-H activation has been developed under metal-free conditions. Both primary and secondary benzylic C-H substrates could react smoothly with various amines to give only mono-amination products with good to

Stereodefined trisubstituted enolates as a unique entry to all-carbon quaternary stereogenic centers in acyclic systems.

Yury Minko et al.

Nature protocols, 8(4), 749-754 (2013-03-23)

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Protective effects of oligomeric and polymeric procyanidin fractions from defatted grape seeds on tert-butyl hydroperoxide-induced oxidative damage in HepG2 cells.

Younghwa Kim et al.

Food chemistry, 137(1-4), 136-141 (2012-12-04)

Oligomeric and polymeric procyanidins have been reported to possess different antioxidant capacities. However, the intracellular antioxidant mechanisms of oligomeric and polymeric procyanidins are still poorly understood. In this study, we evaluated the cytoprotective effects of the oligomeric procyanidin fraction (OPF)

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Número de artículo de comercio global

SKU	GTIN
03-4991-2-25G-J	04061832683676

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