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W237507

Sigma-Aldrich

Diethyl malonate

≥98%, FG

Sinónimos:

Malonic acid diethyl ester

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About This Item

Fórmula lineal:
CH2(COOC2H5)2
Número de CAS:
105-53-3
Peso molecular:
160.17
FEMA Number:
2375
Beilstein/REAXYS Number:
774687
EC Number:
203-305-9
Council of Europe no.:
2106
MDL number:
MFCD00009195
UNSPSC Code:
12164502
PubChem Substance ID:
24901030
Flavis number:
9.490
NACRES:
NA.21

biological source

synthetic

grade

FG
Halal

agency

meets purity specifications of JECFA

reg. compliance

EU Regulation 1334/2008 & 178/2002
FDA 21 CFR 117
FDA 21 CFR 172.515

vapor density

5.52 (vs air)

vapor pressure

1 mmHg ( 40 °C)

assay

≥98%

refractive index

n20/D 1.413 (lit.)

bp

199 °C (lit.)

mp

−51-−50 °C (lit.)

density

1.055 g/mL at 25 °C (lit.)

application(s)

flavors and fragrances

documentation

see Safety & Documentation for available documents

food allergen

no known allergens

organoleptic

apple; green; fruity; sweet

SMILES string

CCOC(=O)CC(=O)OCC

InChI

1S/C7H12O4/c1-3-10-6(8)5-7(9)11-4-2/h3-5H2,1-2H3

InChI key

IYXGSMUGOJNHAZ-UHFFFAOYSA-N

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Categorías relacionadas

General description

Diethyl malonate is an active methylene compound that can be used as a flavoring agent in the food industry.

Application


  • Synthesis and biological activities of novel structural analogues of 2-arachidonoylglycerol, an endogenous cannabinoid receptor ligand.: This study by Suhara et al. focuses on the synthesis of novel structural analogues of 2-arachidonoylglycerol, an endogenous ligand for cannabinoid receptors. The research highlights the utilization of diethyl malonate in the synthesis process, emphasizing its importance in creating biologically active compounds with potential therapeutic applications in modulating cannabinoid receptor activity (Suhara et al., 2001).

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H319

Hazard Classifications

Eye Irrit. 2

Storage Class

10 - Combustible liquids

wgk_germany

WGK 1

flash_point_f

199.4 °F - closed cup

flash_point_c

93 °C - closed cup

ppe

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Encyclopedia of Food and Color Additives, 1, 818-818 (1997)
Encyclopedia of Food and Color Additives, 1, 818-818 (1997)
Lian Jin Liu et al.
Nucleosides, nucleotides & nucleic acids, 30(10), 784-797 (2011-10-05)
Novel 5'-norcarbocyclic adenosine phosphonic acid analogues with 6'-electropositive moiety such as spirocyclopropane were designed and synthesized from the commercially available diethylmalonate 5. Regioselective Mitsunobu reaction proceeded in the presence of an allylic functional group at a low reaction temperature in
Hua Li et al.
Nucleosides, nucleotides & nucleic acids, 29(8), 581-590 (2010-07-28)
This article describes a very simple route for synthesizing novel lipophilic phosphonate bis(t-bu-SATE) prodrugs of acyclic cyclopentenylated nucleosides such as adenine 17 and cytosine 18. The key intermediate 6 was constructed via a ring-closing metathesis of compound 5, which could
Shigeyuki Yamada et al.
Organic & biomolecular chemistry, 5(9), 1442-1449 (2007-04-28)
The addition of heteroaromatic lithium reagents 2 to a THF solution of perfluorocyclopentene (1) provided preferentially the corresponding monosubstituted products 5, while the addition of 1 to 2 effectively gave the 1,2-disubstituted products 6 in good to excellent yields. The
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