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GF83497652

Rhodium

Name: Rhodium
Brand: ALDRICH

wire reel, 0.05m, diameter 1.0mm, as drawn, 99.9%

Sinónimos:

Rhodium, RH005130

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About This Item

Fórmula empírica (notación de Hill):

Número de CAS:

7440-16-6

Peso molecular:

102.91

MDL number:

MFCD00011201

UNSPSC Code:

12141738

PubChem Substance ID:

329812551

NACRES:

NA.23

assay

99.9%

form

wire

manufacturer/tradename

Goodfellow 834-976-52

resistivity

4.33 μΩ-cm, 20°C

L × diam.

0.05 m × 1.0 mm

bp

3727 °C (lit.)

mp

1966 °C (lit.)

density

12.41 g/cm³ (lit.)

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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Categorías relacionadas

High-Purity Metals & Alloys

General description

For updated SDS information please visit www.goodfellow.com.

Legal Information

Product of Goodfellow

Storage Class

13 - Non Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

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Rhodium-catalyzed C-H bond arylation of arenes.

Jean Bouffard et al.

Topics in current chemistry, 292, 231-280 (2010-01-01)

A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms

Domino reactions of rhodium(II) carbenoids for alkaloid synthesis.

Albert Padwa

Chemical Society reviews, 38(11), 3072-3081 (2009-10-23)

In this tutorial review, the rhodium(II)-catalyzed domino reactions of alpha-diazo carbonyl compounds are summarized. The article will emphasize some of the more recent synthetic applications of the rhodium carbenoid cyclization/cycloaddition domino cascade for alkaloid synthesis. The many structurally diverse and

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

Denise A Colby et al.

Chemical reviews, 110(2), 624-655 (2009-05-15)

Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids.

Huw M L Davies et al.

Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)

This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products

The organometallic fluorine chemistry of palladium and rhodium: studies toward aromatic fluorination.

Vladimir V Grushin

Accounts of chemical research, 43(1), 160-171 (2009-10-01)

Although springing from two established fields, organometallic chemistry and fluorine chemistry, organometallic fluorine chemistry is still in its early stages. However, developments in this area are expected to provide new tools for the synthesis of selectively fluorinated organic compounds that

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