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GF37380089

Rhodium

Name: Rhodium
Brand: ALDRICH

wire reel, 0.2m, diameter 0.25mm, hard, 99.9%

Sinónimos:

Rhodium, RH005110

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About This Item

Fórmula empírica (notación de Hill):

Número de CAS:

7440-16-6

Peso molecular:

102.91

MDL number:

MFCD00011201

UNSPSC Code:

12141738

PubChem Substance ID:

329805678

NACRES:

NA.23

assay

99.9%

form

wire

manufacturer/tradename

Goodfellow 373-800-89

resistivity

4.33 μΩ-cm, 20°C

L × diam.

0.2 m × 0.25 mm

bp

3727 °C (lit.)

mp

1966 °C (lit.)

density

12.41 g/cm³ (lit.)

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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Categorías relacionadas

Metales y aleaciones de gran pureza

General description

For updated SDS information please visit www.goodfellow.com.

Legal Information

Product of Goodfellow

Storage Class

13 - Non Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Domino reactions of rhodium(II) carbenoids for alkaloid synthesis.

Albert Padwa

Chemical Society reviews, 38(11), 3072-3081 (2009-10-23)

In this tutorial review, the rhodium(II)-catalyzed domino reactions of alpha-diazo carbonyl compounds are summarized. The article will emphasize some of the more recent synthetic applications of the rhodium carbenoid cyclization/cycloaddition domino cascade for alkaloid synthesis. The many structurally diverse and

103Rh NMR spectroscopy and its application to rhodium chemistry.

Jan Meine Ernsting et al.

Magnetic resonance in chemistry : MRC, 42(9), 721-736 (2004-08-13)

Rhodium is used for a number of large processes that rely on homogeneous rhodium-catalyzed reactions, for instance rhodium-catalyzed hydroformylation of alkenes, carbonylation of methanol to acetic acid and hydrodesulfurization of thiophene derivatives (in crude oil). Many laboratory applications in organometallic

Remote C-H activation via through-space palladium and rhodium migrations.

Feng Shi et al.

Topics in current chemistry, 292, 123-164 (2010-01-01)

The catalytic activation of a C-H bond is a fundamentally important organic transformation. There are now numerous reports of palladium-mediated C-H activation by the through-space interaction of a palladium center with a neighboring C-H bond. This type of C-H activation

Guiding principles for site selective and stereoselective intermolecular C-H functionalization by donor/acceptor rhodium carbenes.

Huw M L Davies et al.

Chemical Society reviews, 40(4), 1857-1869 (2011-03-02)

This tutorial review presents a description of the controlling elements of intermolecular C-H functionalization by means of C-H insertion by donor/acceptor rhodium carbenes. These rhodium carbenes, readily derived from the combination of diazo compounds with dirhodium(ii) catalysts, are sufficiently reactive

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

Denise A Colby et al.

Chemical reviews, 110(2), 624-655 (2009-05-15)

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