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GF33789550

Rhodium

Name: Rhodium
Brand: ALDRICH

foil, not light tested, 50x50mm, thickness 0.001mm, permanent polyester support, 99.85%

Sinónimos:

Rhodium, RH000190

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About This Item

Fórmula empírica (notación de Hill):

Número de CAS:

7440-16-6

Peso molecular:

102.91

MDL number:

MFCD00011201

UNSPSC Code:

12141738

PubChem Substance ID:

329805125

NACRES:

NA.23

assay

99.85%

form

foil

manufacturer/tradename

Goodfellow 337-895-50

resistivity

4.33 μΩ-cm, 20°C

size × thickness

50x50 mm × 0.001 mm

bp

3727 °C (lit.)

mp

1966 °C (lit.)

density

12.41 g/cm³ (lit.)

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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General description

For updated SDS information please visit www.goodfellow.com.

Legal Information

Product of Goodfellow

Storage Class

13 - Non Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

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Rhodium-catalyzed C-H bond arylation of arenes.

Jean Bouffard et al.

Topics in current chemistry, 292, 231-280 (2010-01-01)

A review is presented of synthetic methods for the preparation of biaryls by the rhodium-catalyzed C-H bond arylation of arenes with aryl halides (C-H/ C-X couplings), arylmetal reagents (C-H/C-M couplings) and arenes (C-H/C-H couplings), with an emphasis on postulated mechanisms

Domino reactions of rhodium(II) carbenoids for alkaloid synthesis.

Albert Padwa

Chemical Society reviews, 38(11), 3072-3081 (2009-10-23)

In this tutorial review, the rhodium(II)-catalyzed domino reactions of alpha-diazo carbonyl compounds are summarized. The article will emphasize some of the more recent synthetic applications of the rhodium carbenoid cyclization/cycloaddition domino cascade for alkaloid synthesis. The many structurally diverse and

Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation.

Denise A Colby et al.

Chemical reviews, 110(2), 624-655 (2009-05-15)

Intermolecular reactions of electron-rich heterocycles with copper and rhodium carbenoids.

Huw M L Davies et al.

Chemical Society reviews, 36(7), 1109-1119 (2007-06-20)

This tutorial review describes the reactions of the electron-rich heterocycles pyrrole, furan, indole and benzofuran with copper and rhodium carbenoids. Two main reaction pathways are possible, involving either a concerted non-synchronous cyclopropanation or zwitterionic intermediates. A diverse range of products

Ligands for practical rhodium-catalyzed asymmetric hydroformylation.

Jerzy Klosin et al.

Accounts of chemical research, 40(12), 1251-1259 (2007-11-14)

A series of bis-phosphite and bis-phosphine ligands for asymmetric hydroformylation reactions has been evaluated. Bis-phosphite ligands lead, in general, to high regioselectivities across a range of substrates while good enantioselectivities are limited to only a few examples. We found that

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