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B56501

Sigma-Aldrich

4-Bromoanisole

≥99.0%

Sinónimos:

1-Bromo-4-methoxybenzene

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50 G
$41.30
100 G
$50.32
500 G
$165.00

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50 G
$41.30
100 G
$50.32
500 G
$165.00

About This Item

Fórmula lineal:
BrC6H4OCH3
Número de CAS:
104-92-7
Peso molecular:
187.03
Beilstein:
1237590
Número CE:
203-252-1
Número MDL:
MFCD00000097
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
24891850
NACRES:
NA.22

$41.30

Disponible para envío el23 de abril de 2025Detalles

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Nivel de calidad

100

Ensayo

≥99.0%

Formulario

liquid

índice de refracción

n20/D 1.564 (lit.)

bp

223 °C (lit.)

mp

9-10 °C (lit.)

densidad

1.494 g/mL at 25 °C (lit.)

cadena SMILES

COc1ccc(Br)cc1

InChI

1S/C7H7BrO/c1-9-7-4-2-6(8)3-5-7/h2-5H,1H3

Clave InChI

QJPJQTDYNZXKQF-UHFFFAOYSA-N

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Descripción general

4-Bromoanisole is a useful brominating reagent.[1] It is formed as reaction product in the reaction between HOBr and anisole.[2] Suzuki coupling of 4-bromoanisole with phenylboronic acid catalyzed by palladium pincer complexes has been studied.[3] Heck Reaction of 4-bromoanisole with ethyl acrylates in room-temperature ionic liquids is reported to afford ethyl 4-methoxycinnamate.[4]

Aplicación

4-Bromoanisole was used in the synthesis of aryl 1,3-diketones.[5]

Pictogramas

Exclamation mark
GHS07

Palabra de señalización

Warning

Frases de peligro

H302,H315

Clasificaciones de peligro

Acute Tox. 4 Oral - Skin Irrit. 2

Código de clase de almacenamiento

10 - Combustible liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

201.2 °F

Punto de inflamabilidad (°C)

94 °C

Equipo de protección personal

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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Certificados de análisis (COA)

Lot/Batch Number
SDBB2192
STBL3101
STBK2893
STBJ3720
STBH8191

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Sigma-Aldrich

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Sigma-Aldrich

417599

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Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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