923443

PhMPhos

• Sinónimos: 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene
• Fórmula empírica (notación de Hill): C₄₂H₄₈FeP₂
• Peso molecular: 670.62
• UNSPSC Code: 12352200
• NACRES: NA.21

Propiedades

• form: powder
• Quality Level: 100
• reaction suitability: reagent type: catalyst; reaction type: Cross Couplings; reagent type: ligand
• functional group: phosphine

Descripción

Application

PhMPhos is an unsymmetrical ferrocene-based phosphine ligand. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. Pd catalysts containing PhMPhos can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

Other Notes

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

Información de seguridad

• Storage Class: 11 - Combustible Solids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable