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Documentos

903167

Sigma-Aldrich

10-Phenylphenothiazine

≥95%

Sinónimos:

10-Phenyl-10H-phenothiazine, N-Phenylphenothiazine

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About This Item

Fórmula empírica (notación de Hill):
C18H13NS
Número de CAS:
7152-42-3
Peso molecular:
275.37
MDL number:
MFCD00156238
UNSPSC Code:
12352005
NACRES:
NA.22

assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Photocatalysis

mp

94 °C

photocatalyst activation

365 nm

SMILES string

C12=CC=CC=C1SC3=C(C=CC=C3)N2C4=CC=CC=C4

InChI

1S/C18H13NS/c1-2-8-14(9-3-1)19-15-10-4-6-12-17(15)20-18-13-7-5-11-16(18)19/h1-13H

InChI key

WSEFYHOJDVVORU-UHFFFAOYSA-N

Application

An organic photo-catalyst used in synthesis of small molecules as well as polymerization reactions.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Catalytic Defluoroalkylation of Trifluoromethylaromatics with Unactivated Alkenes

Single-Ion Homopolymer Electrolytes with High Transference Number Prepared by Click Chemistry and Photoinduced Metal-Free Atom-Transfer Radical Polymerization

related product

Referencia del producto
Descripción
Precios

46624

Phenothiazine, VETRANAL®, analytical standard

901112

PhenN O-PC™ B0301, New Iridium, ≥97%

901111

Phenox O-PC™ A0202, New Iridium, ≥97%

908444

DPZ, 95%

916722

Phenyl-(benzo)phenothiazine

922641

Pr-DMQA[BF4], ≥95%

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Honghong Gong et al.
Angewandte Chemie (International ed. in English), 57(1), 333-337 (2017-11-15)
Fluorinated polymers are important materials that are widely used in many areas. Herein, we report the development of a metal-free photocontrolled radical polymerization of semifluorinated (meth)acrylates with a new visible-light-absorbing organocatalyst. This method enabled the production of a variety of
Single-Ion Homopolymer Electrolytes with High Transference Number Prepared by Click Chemistry and Photoinduced Metal-Free Atom-Transfer Radical Polymerization.
Li. S, et al.
ACS Energy Letters, 3(1), 20-27 (2018)
Hengbin Wang et al.
Journal of the American Chemical Society, 140(1), 163-166 (2017-12-20)
We describe a new catalytic approach to selective functionalization of the strong C-F bonds in trifluoromethylaromatic (Ar-CF3) systems. In this approach, single electron reduction of Ar-CF3 substrates (using a photoredox catalyst) results in difluorobenzylic radical formation through a C-F cleavage
Mao Chen et al.
ACS central science, 3(2), 124-134 (2017-03-11)
Light-initiated additive manufacturing techniques typically rely on layer-by-layer addition or continuous extraction of polymers formed via nonliving, free radical polymerization methods that render the final materials "dead" toward further monomer insertion; the polymer chains within the materials cannot be reactivated
Organocatalyzed Photoredox Polymerization from Aromatic Sulfonyl Halides: Facilitating Graft from Aromatic C-H bonds.
Zhao Y, et al.
Macromolecules, 51(3), 938-946 (2018)
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