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900152

Sigma-Aldrich

2-[[(2-Carboxyethyl)sulfanylthiocarbonyl]-sulfanyl]propanoic acid

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About This Item

Fórmula empírica (notación de Hill):
C7H10O4S3
Número de CAS:
870451-09-5
Peso molecular:
254.35
MDL number:
MFCD28126761
UNSPSC Code:
12352106
PubChem Substance ID:
329769779
NACRES:
NA.23

assay

95% (GC)

Quality Level

100

form

powder

mp

120-125 °C

General description

  • A stable, trithiocarbonate chain transfer agent (CTA), also referred to as a RAFT agent, which can control chain growth in free radical polymerization producing polymers with well-defined molecular weights and low polydispersities.
  • 2-(2-Carboxyethylsulfanylthiocarbonylsulfanyl)propionic acid may be used to control homo- and co-polymerization of acrylic acid, acrylates, acrylamides, styrenes, methacrylates, and methacrylamides. It is soluble in aqueous and organic media (amphiphilic).

Caution

Storage conditions: Room temperature, protect from light.

Legal Information

Sold for research purposes only: See sigma-aldrich.com/raftlicense. Patents: WO98/01478, WO99/311444.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Synthesis and Evaluation of New Dicarboxylic Acid Functional Trithiocarbonates: RAFT Synthesis of Telechelic Poly(n-butyl acrylate)s.
Wang R, et al.
Macromolecules, 38, 9518-9525 (2005)
Synthesis of Dual-Functional Poly(6-azidohexylmethacrylate) Brushes by a RAFT Agent Carrying Carboxylic Acid End Groups.
Cimen D, et al.
Journal of Polymer Science Part A: Polymer Chemistry, 53, 1696-1706 (2015)
Substituent Effects on Trithiocarbonates-Mediated Polymerization of Styrene.
Journal of Applied Polymer Science, 111, 2011-2017 (2009)
A Continuous Flow Process for the Radical Induced End Group Removal of RAFT Polymers.
Hornung H, et al.
Macromolecular Reaction Engineering, 6, 246-251 (2012)
RAFT Inverse Miniemulsion Polymerization of Acrylic Acid and Sodium Acrylate.
Ouyang L, et al.
Macromolecular Reaction Engineering, 5, 163-169 (2011)
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